Diamond in nanoparticle form is a promising material that can be used as a robust and chemically stable catalyst support in fuel cells. It has been studied and characterized physically and electrochemically, in its thin film and powder forms, as reported in the literature. In the present work, the electrochemical properties of undoped and boron-doped diamond nanoparticle electrodes, fabricated using the ink-paste method, were investigated. Methanol oxidation experiments were carried out in both half-cell and full fuel cell modes. Platinum and ruthenium nanoparticles were chemically deposited on undoped and boron doped diamond nanoparticles through the use of NaBH(4) as reducing agent and sodium dodecyl benzene sulfonate (SDBS) as a surfactant. Before and after the reduction process, samples were characterized by electron microscopy and spectroscopic techniques. The ink-paste method was also used to prepare the membrane electrode assembly with Pt and Pt-Ru modified undoped and boron-doped diamond nanoparticle catalytic systems, to perform the electrochemical experiments in a direct methanol fuel cell system. The results obtained demonstrate that diamond supported catalyst nanomaterials are promising for methanol fuel cells.

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The increasing number, size, and complexity of nuclear facilities deployed worldwide are increasing the need to maintain readiness and develop innovative sensing materials to monitor important to safety structures (ITS) such as pressure vessels and piping (PVP) in a nuclear reactor. Technologies for the diagnosis and prognosis of PVP systems can improve verification of the health of the structure that can eventually reduce the likelihood of inadvertently failure. Recently investigated piezoelectric wafer active sensors (PWAS) open the possibilities to develop and deploy such system. Piezoelectric wafer active sensors are widely used in structural health monitoring (SHM) to determine the presence of cracks, delaminations, disbonds, and corrosion. Durability and survivability of PWAS under environmental exposures has been tested before. However the irradiation effects, pertinent to nuclear facilities for PWAS, have not been studied yet. This paper presents a study on PWAS that exposed to high energy gamma radiation. PWAS were irradiated using a Co-60 gamma source in an irradiator with different exposure times. The dose rate and total absorbed dose were calculated using Monte Carlo simulations (MCNPX). The PWAS material properties, electrical contact change were characterized through a series of tests. The electro-mechanical impedance spectrum (EMIS) of PWAS was measured before and after irradiation. This study not only provides the fundamental understanding of the PWAS irradiation survivability but also tests the potential of PWAS as irradiation sensors for nuclear applications.

The piezoresistivity and the micro fabrication capability have made the polymer derived ceramics (PDCs) an excellent candidate material for high temperature sensors. In this study, it was found that PDCs also exhibit creep and stress relaxation properties. Its electric resistance may change with time under certain loading conditions. In addition, the creep/stress relaxation rate is sensitive to temperature. It is demonstrated that even PDC materials have been processed at high temperatures and formed ceramic structure, they retain certain polymeric characteristics. Due to the piezoresistivity properties of PDC and its resilience to harsh environment, in particular, the predicted resistance to radiation field, the PDC based sensors are ideal for use as sensing media that can be deployed to important to safety (ITS) structures in nuclear systems, such as cooling water system and coolant pumps in light water reactors (LWRs).

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