The particle transport through a chain of quantum dots coupled to two bosonic reservoirs is studied. For the case of reservoirs of non-interacting bosonic particles, we derive an exact set of stochastic differential equations, whose memory kernels and driving noise are characterised entirely by the properties of the reservoirs. Going to the Markovian limit an analytically solvable case is presented. The effect of interparticle interactions on the transient behaviour of the system, when both reservoirs are instantaneously coupled to an empty chain of quantum dots, is approximated by a semiclassical method, known as the Truncated Wigner approximation. The steady-state particle flow through the chain and the mean particle occupations are explained via the spectral properties of the interacting system.

We extend the Nakajima-Zwanzig projection operator technique to the determination of multitime correlation functions of open quantum systems. The correlation functions are expressed in terms of certain multitime homogeneous and inhomogeneous memory kernels for which suitable equations of motion are derived. We show that under the condition of finite memory times these equations can be used to determine the memory kernels by employing an exact stochastic unraveling of the full systemenvironment dynamics. The approach thus allows to combine exact stochastic methods, feasible for short times, with long-time master equation simulations. The applicability of the method is demonstrated by numerical simulations of 2D-spectra for a donor-acceptor model, and by comparison of the results with those obtained from the reduced hierarchy equations of motion. We further show that the formalism is also applicable to the time evolution of a periodically driven two-level system initially in equilibrium with its environment.

We modify the path integral representation of exciton transport in open quantum systems such that an exact description of the quantum fluctuations around the classical evolution of the system is possible. As a consequence, the time evolution of the system observables is obtained by calculating the average of a stochastic difference equation which is weighted with a product of pseudoprobability density functions. From the exact equation of motion one can clearly identify the terms that are also present if we apply the truncated Wigner approximation. This description of the problem is used as a basis for the derivation of a new approximation, whose validity goes beyond the truncated Wigner approximation. To demonstrate this we apply the formalism to a donor-acceptor transport model.

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