The structure of mixed cements with mineral additives of different nature enables to divide them into two types: with single-stage and multi-stage structure formation. Characterization of mixed cements is determined, mainly, by nature of the mineral admixture. The index of multi-stage structure formation of mixed cements has been suggested. This index is the value of instantaneous power of structure formation Wη. It has been shown that in case of the other equal conditions the nature of structure formation is determined by the ratio of the components and by milling method of the mixed cement. As a result of analysis of numerous experimental data it has been detected, that the strength of stone, which is formed during hardening of mixed cements, has an extreme nature depending on the content of the mineral admixture. Analysis of the thermodynamic stability of the structure of the stone, which is formed in the process of hardening of mixed cements, allows to divide mixed cements into three groups and identify field of their rational use.
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