A solid solution of bismuth cobalt titanate [Bi(Co0.5Ti0.5)O3] and bismuth ferrite (BiFeO3) with a composition Bi(Co0.40Ti0.40Fe0.20)O3 (abbreviated as BCTF80/20) was synthesized via a cost effective solid-state technique.

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This paper reports the synthesis and magnetic properties of single phase FeTiO3nanoparticles. Ilmenite nanoparticles are prepared through coprecipitation method. As prepared powder is amorphous in nature. When annealed inair and inert atmosphere, we get almost single phase pure crystalline FeTiO3. Our results show that FeTiO3in nanocrystalline form behaves like a weak ferromagnet below ~50 K while it is known that ilmenite is an antiferromagnet below ~55 K.

Materials of Ti doped nanocrystalline SrFeO3-δ were synthesized through solid state reaction. Detailed magnetization measurements were carried out in zero field cooled (ZFC) and field cooled (FC) conditions. Compounds of SrFe1-xTixO3-δ (x = 0.1 to 0.3) are found to be spin glass and parent compound is a helical antiferromagnet. Non magnetic Ti4+ reduces the strength of exchange interactions and the curvature of hysteresis is changed towards concave nature. Exchange bias is observed below the peak temperature (irreversibility in magnetization (TIrr)) in ZFC-FC of SrFe1-xTixO3-δ (x = 0 to 0.3). The coercivity and exchange bias field values are found to be decreases with increase in temperature. Observed exchange bias effect is attributed to competition between antiferromagnetic superexchange and ferromagnetic double exchange interactions.

LaFeO3 nanocrystalline ferrites were synthesized through sol-gel method in different size distributions and the effect of finite size on magnetic properties is investigated. Results of magnetization and Mössbauer measurements show that superparamagnetism and weak ferromagnetic behavior in some of the size distributions. The origin of the superparamagnetism is from fine particles similar to ferromagnetic single domains and the weak ferromagnetism comes from surface spin disorder caused by Dzyaloshinskii-Moriya interaction. The magnetic ground state of LaFeO3 nanoparticles differs from that of bulk, and the ground state is dictated by the finite size effect because density of states depends on the dimensionality of the sample.