This study was conducted by analyzing the effect of surface treatment on wool using varying percentages of protease (3%, 6%, and 9%) with incorporating silver nanoparticles and by varying pH (i.e., pH = 4 and pH = 7). The comparison of fiber surface morphology and the FTIR analysis was done to characterize the nanocoating. The results showed that the antistatic and antibacterial effect on the samples treated at 3% protease and 6% protease were better than the samples treated at 9% protease. Correspondingly, the samples treated at pH 4 had better antistatic and antibacterial properties than those treated at pH 7. Sulfur compounds play a key role in interaction and absorption of silver nanoparticles.

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Nanoscale polyelectrolyte complex materials have been extensively investigated for their promising application in protocell, drug carriers, imaging, and catalysis. However, the conventional preparation approach involving positive and negative polyelectrolytes leads to large size, wide size distribution, instability, and aggregation due to the nonhomogeneous mixing process. Herein, we employ reactive flash nanoprecipitation (RFNP) to control the mixing and preparation of the nanoscale polyelectrolyte complex. With RFNP, homogeneous mixing complexation between oppositely charged chitosan derivatives could be achieved, resulting in stable nanoscale complexes (NCs) with controllable size and narrow size distribution. The smallest size of NCs is found at specific pH due to the maximum attraction of positive and negative molecules of chitosan. The size can be modulated by altering the volumetric flow rates of inlet streams, concentration, and charge molar ratio of two oppositely charged chitosan derivatives. The charge molar ratio is also tuned to create NCs with positive and negative shells. There is no significant variation in the size of NCs produced at different intervals of time. This method allows continuous and tunable NC production and could have the potential for fast, practical translation.