Metallic glasses are known for their mechanical properties but lack plasticity. This could be prevented by combining them with other materials or by inducing a second phase to form a composite. These composites have enhanced thermo-physical properties. The review paper aims to outline a summary of the current research done on metallic glass and its composites. A background in the history, properties, and their applications is discussed. Recent developments in biocompatible metallic glass composites, fiber-reinforced metallic glass, ex situ and in situ, are discussed.

The single-phase multi-principal-component CoFeMnTiVZr alloy was obtained by rapid solidification and examined by a combination of electrochemical methods and gas–solid reactions.

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In this work, the biomedical applicability and physical properties of magnesium-based metallic glass/polycaprolactone (PCL) composites are explored. The composites were fabricated via mechanical alloying and subsequent coextrusion. The coextrusion process was carried out at a temperature near to the supercooled liquid region of the metallic glass and the viscous region of the polymer. The structures, as well as thermal and mechanical properties of the obtained samples were characterized, and in vivo investigations were undertaken. The composite samples possess acceptable thermal and mechanical properties. Tensile tests indicate the ability of the composites to withstand more than 100% deformation. In vivo studies reveal that the composites are biologically compatible and could be promising for biomedical applications.

Composites based on Zr65Cu17.5Ni10Al7.5 metallic glass (MG) and polytetrafluoroethylene (PTFE) were prepared by ball milling. Different composites (30/70, 50/50 and 70/30) were produced. Samples for dynamic mechanical analysis and laser flash analysis were fabricated in the supercooled region of the metallic glass and viscous region of the polymer. Spark plasma sintering (SPS) was performed at the supercooled region for the metallic glass powder. Characteristics such as thermal, mechanical, and structural properties were studied. A formation of the Zr2Cu and Zr2Ni intermetallic was found in the metallic glass after SPS. A formation of the nanocrystalline Zr2Cu was found in composite samples. Dynamical mechanical analysis (DMA) was used to study the mechanical behavior of the material. It was concluded that the 70/30-MG/PTFE composite sample had better thermal conductivity than the other composite samples. The thermal conductivity of the metallic glass was the highest among the samples and it increased with the MG content in composites.