Magmatic systems play a crucial role in enriching the crust with volatiles and elements that reside primarily within the Earth's mantle, including economically important metals like nickel, copper and platinum-group elements. However, transport of these metals within silicate magmas primarily occurs within dense sulfide liquids, which tend to coalesce, settle and not be efficiently transported in ascending magmas. Here we show textural observations, backed up with carbon and oxygen isotope data, which indicate an intimate association between mantle-derived carbonates and sulfides in some mafic-ultramafic magmatic systems emplaced at the base of the continental crust. We propose that carbon, as a buoyant supercritical CO 2 fluid, might be a covert agent aiding and promoting the physical transport of sulfides across the mantle-crust transition. This may be a common but cryptic mechanism that facilitates cycling of volatiles and metals from the mantle to the lower-to-mid continental crust, which leaves little footprint behind by the time magmas reach the Earth's surface.

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There are numerous examples of fault-controlled, so-called hydrothermal dolomite (HTD), many of which host economic mineral deposits or hydrocarbons, but there remains a lack of consensus as to how they form. In particular, multiple phases of diagenetic overprinting can obscure geochemical fingerprints. Study of a Cenozoic succession with a relatively simple burial history here provides new insights into the development of differentially dolomitized beds. The Hammam Faraun fault (HFF) block within the Suez Rift, Egypt, hosts both massive and stratabound dolostone bodies. Non-fabric-selective massive dolostone is limited to the damage zone of the fault, while fabric-selective stratabound dolostone bodies penetrate nearly 2 km into the footwall. Oligo-Miocene seawater is interpreted to have been drawn down discrete faults into a deep aquifer and convected upwards along the HFF. Escape of fluids from the incipient HFF into the lower Thebes Formation led to differential, stratabound dolomitization. Once the HFF breached the surface, fluid circulation focused along the fault plane to form younger, massive dolostone bodies. This study provides a snapshot of dolomitization during the earliest phases of extension, unobscured by subsequent recrystallization and geochemical modification. Contrary to many models, stratabound dolomitization preceded non-stratabound dolomitization. Fluids were hydrothermal, but with little evidence for rapid cooling and brecciation common to many HTD bodies. These results suggest that many of the features used to interpret and predict the geometry of HTD in the subsurface form during later phases of structural deformation, perhaps overprinting less structurally complex dolomite bodies.

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As the decarbonisation of heating and cooling becomes a matter of critical importance, it has been shown that flooded mines can provide a reliable source of low-carbon thermal energy production and storage when coupled with appropriate demand via an appropriate heat transfer technology. This paper summarises the potential resource represented by a long legacy of mining operations, the means heat can be extracted from (or rejected to) flooded mine workings, and then considers the risks and challenges faced by minewater geothermal energy (MWG) schemes in the planning, construction, and operational phases. A combination of site visits, interviews and literature reviews has informed concise, updated accounts for many of the minewater geothermal energy systems installed across the world, including accounts of hitherto unpublished systems. The paper has found that a number of previously reported MWG schemes are now non-operational. Key risks encountered by MWG schemes (which in some cases have led to decommissioning) include clogging of system components with mineral precipitates (e.g., ochre), uncertainty in targeting open mine voids and their hydraulic behaviour, uncertainty regarding longevity of access to minewater resource, and accumulated ongoing monitoring and maintenance burdens.