Ineffectiveness of the chemicals applied so far for waterlogged wood conservation created the need to develop new more, efficient and reliable agents. As an alternative, a new method with the use of organosilicon compounds differing in chemical composition and molecular weight has been investigated. The results obtained show the potential of organosilicons as consolidants in waterlogged wood conservation able to effectively stabilise wood dimensions upon drying. The best wood stabilisers were low-molecular organosilicons enable to penetrate the cell wall as well as chemicals with functional groups capable of interacting with wood polymers and forming stabilising coatings on the cell wall surface. The best anti-shrink efficiency values were obtained for (3-Mercaptopropyl)trimethoxysilane, (3-Aminopropyl)triethoxysilane, 1,3-Bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane, reaching 98, 91 and 91%, respectively. Most of the applied organosilicons reduced wood hygroscopicity, which limits the risk of further dimensional changes of wood exposed to a variable air moisture content and potentially reduces wood biodegradation. In the light of our studies, the proposed method of waterlogged wood conservation with organosilicons is potentially reversible in the case of siloxanes and amino-silanes as well as retreatable, which complies with the requirements of the conservation ethics.
Hydrophobization of cotton fabrics was carried out with the use of bifunctional polysiloxanes with various contents of functional groups. Polysiloxanes contained in their structure groups capable of bonding to substrates (trialkoxysilyl or glycidyl ones) and fluoroalkyl groups showing surface activity. Two methods of surface modification were compared: (1) a one-step method via the chemical modification of fabrics with solutions of bifunctional polysiloxanes and (2) a two-step method-via preliminary modification of fabrics with silica sol followed by chemical modification with solutions of bifunctional polysiloxanes. The hydrophobicity was determined by measuring the water contact angle by drop profile tensiometry. Changes in the surface topography were examined by scanning electron microscopy. Superhydrophobic fabrics were obtained by a simple one-step method by the chemical modification in solutions of bifunctional polysiloxanes. The fabrics maintained their superhydrophobic properties even after multiple washings. The modification does not cause any changes visible to the naked eye, such as stiffening, color changes or a decrease in mechanical properties.
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