We have reacted Georgia marble in sulfur dioxide (S02) enriched atmospheres and calcul~ted the reaction rate constant. This constant was denved from surface reduction data, obtained by leaching the reaction product from samples exposed for different periods of time. Application of this constant to marble weathered in known ambient levels of sulfur dioxid~(SO2) and relative humidity, .allows the prediction of the thickness of the resulting gypsum crust formed over a given period of time. We have found that the crust grows outwards due to calcium ions which migrate from the interior and then react with sulfur dioxide at the sample surface. Thus, any treatment of the sulfated marble should include the considerations that the crust only masks the marble surface and is not an integral part of the original sculpture, and that cavities exist in~he u:nderlying layer of marble from which the calcIum Ions were selectively depleted.
A broth containing the sulfate reducing bacterium Desulfovibrio desulfuricans was used to treat samples of reagent calcium sulfate, gypsum-ro.ck specimens, fragments from a marble monument wIth a black weathering crust rich in gypsum, and a marble monument with similar crust. Calcite was found to have formed on all treated surfaces suggesting that this microbe has the potential to clean crusted marble monuments whilst also regenerating calcite, the parent mineral of the marble.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.