GaN-on-diamond device cooling can be enhanced by reducing the effective thermal boundary resistance (TBR) of the GaN/diamond interface. The thermal properties of this interface and of the polycrystalline diamond grown onto GaN using SiN and AlN barrier layers as well as without any barrier layer under different growth conditions are investigated and systematically compared for the first time. TBR values are correlated with transmission electron microscopy analysis, showing that the lowest reported TBR (∼6.5 m K/GW) is obtained by using ultrathin SiN barrier layers with a smooth interface formed, whereas the direct growth of diamond onto GaN results in one to two orders of magnitude higher TBR due to the formation of a rough interface. AlN barrier layers can produce a TBR as low as SiN barrier layers in some cases; however, their TBR are rather dependent on growth conditions. We also observe a decreasing diamond thermal resistance with increasing growth temperature.
An epitaxial lift‐off (ELO) process for GaN materials has been demonstrated using bandgap‐selective photoenhanced wet etching of an InGaN release layer. This process has been applied to GaN layers grown on sapphire as well as native GaN substrates using a perforation technique to scale the process up to wafers of arbitrary size. The process has the advantage of leveraging conventional MOCVD growth to form the release layer, with minimal degradation of films grown on top of the release layer. The ELO process is non‐destructive and can enable cost reduction through reuse of the native GaN substrate after ELO. The GaN films have been characterized before and after ELO using AFM, SEM, XRD, TEM and by fabricating Schottky barrier diodes. The performance of Schottky diodes fabricated on GaN‐on‐sapphire structures was found to improve after ELO. Potential applications for this technology include GaN power and optoelectronic devices as well as flexible electronics.
Shown is a 5‐micron‐thick GaN epitaxial film released from a 4‐inch sapphire substrate using perforations on a 1‐mm pitch. The yellow luminescence of the nitrogen face of the released film is visible under ultraviolet illumination.
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