Thermoplastic resins used as a matrix of fiber reinforced thermoplastics (FRTPs) are composed of high polymers that remain highly viscous even at a higher temperature than their melting points. As a result, they need an even higher temperature, a higher pressure and a longer processing time to allow them to bond with fibers that require large and specialized equipment. In contrast, fiber-reinforced thermoset plastics (FRPs) can be easily molded owing to the use of lower viscosity liquid resin as the matrix using simpler devices. In this paper, a new fabrication method of FRTPs using in situ polymerizable ε caprolactam as the matrix is presented. This method uses vacuum-assisted resin transfer molding without the need for large and specialized equipment. The ε -caprolactam molecules were converted from their monomer form into a polyamide 6 resin, with ring-opening polymerization of ε -caprolactam during the molding process at a lower temperature than its melting temperature. The two kinds of FRTPs obtained using ε -caprolactam as the matrix had neither voids nor unfilled parts because ε -caprolactam had a very low viscosity before the polymerization. These FRTPs not only exhibit superior bending properties but also are suitable for high-speed molding, namely, within a few minutes of process time.

Conventional fiber reinforced plastics (FRPs) have some problems in the case of disposal. Their combustion disposal discharges the carbon dioxide in the air because resins of FRPs are made of fossil fuel. In the case of disposal into the ground, these FRPs remain semi-permanently without decomposing. Therefore, green composites are now developed and are studied as one of less the environmental burden materials. In this study, two kinds of continuous green composite sheets, which were composed of Kenaf fibers or Linen fibers as reinforcement and biodegradable poly butylene succinate (PBS) resin as a matrix, were fabricated with a pultrusion molding. Since the PBS resin is a thermoplastic resin, the PBS/KENAF or PBS/ LINEN composite sheets can be treated as intermediate materials such as Carbon Fiber Reinforced Plastic prepregs. In order to apply the PBS/KENAF or PBS/LINEN composite sheets to structural components, quasi-isotropic plates and cylindrical shells were fabricated and evaluated.

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