Nowadays in the world, due to the constant desire for recycling, many countries are considering the use of recycled plastics on roads. Modification of bitumen for roads in Kazakhstan is considered one of the most suitable and popular approaches. This paper presents the results of research on the modification of bitumen by recycled plastics from waste materials. The paper describes the details of the use of plastic waste as bitumen modifiers, with a specific focus on recycled plastics and how they can potentially be used to enhance bitumen performance and the road durability. The main physical and mechanical characteristics of the modified bitumen were determined after routine tests, penetration and plasticity, softening temperature, brittleness temperature on Fraas and microscopic analysis. The morphology of the modified bitumen was studied using scanning electron microscopy. The results confirm that the modified bitumen complies with the requirements for polymer-bitumen binder of Kazakhstani standards and is suitable for the production of modified bitumen by its physical and chemical characteristics.
The article presents the results of research on the production of polymer-bitumen binder (PBB) based on mixtures of non-oxidized and oxidized petroleum products, namely high-viscosity tar, darkened vacuum distillate, and oxidized petroleum bitumen 70/100, obtained at technological installations of Limited Liability Partnership (LLP) “JV Caspi Bitum’’ and styrene-butadiene-styrene (SBS) block copolymer brand L 30-01A modifier in the presence of a stabilizer. The results obtained show that the introduction of the SBS modifier in the presence of a sulfur stabilizer improves the performance characteristics of PBB, such as elasticity, ductility, softening temperature, penetration, and brittleness temperature.
A literature review on the topic of the study has shown that there is not much work with the use of oily waste in the modification of bitumen. Many methods of bitumen modification include the oxidation of a heavy oil residue to obtain the target product and its further compounding with the finished bitumen. Old oil sludge from oil sludge storage tanks has been used as the oil residue. Oil sludge is prepared by dehydration, the water content should not exceed no more than 5 wt. % and separation of mechanical impurities up to a content of not more than 16.4 wt. %. Purpose of the work. The main objective of the study is to develop a technology for modifying oil bitumen with industrial waste for the disposal of oil sludge, and to show the possibility of improving the physical-chemical, rheological characteristics of modified bitumen. Results. In the process of bitumen modification, the physical-chemical characteristics of the modified bitumen have been studied. It has been established that the composition of oil sludge from the Uzen and Zhetybai oilfield of the Mangistau region contains a significant amount of heavy oil residues and a small amount of mechanical impurities. From the conducted laboratory esearch, it has been found that oil sludge can be used as a filler in the modification of bitumen. Conclusion. Used oil sludge can be used as a bituminous base modifier without removing the mechanical impurities. Polymer-bitumen compositions have been prepared and the optimal parameters for the process of preparing polymer-bitumen binders have been determined.
It is proposed to use plastic waste as bitumen modifiers with a special emphasis on recycled plastics. The potential use for improving the characteristics of bitumen and durability of roads is being considered. For the preparation of modified bitumen, it was used the BND 100/130 bitumen produced by LLP "JV CASPI BITUMEN" (Kazakhstan). Polymer household waste based on plastic bottles was used as objects of the research. Polymer waste was obtained by mechanical recycling. The main physical and mechanical characteristics of the modified bitumen were determined after routine tests, penetration and plasticity, softening temperature, Fraas brittleness temperature and microscopic analysis. The morphology of the modified bitumen was studied using scanning electron microscopy. An original formulation of the polymer-bitumen binder with improved performance characteristics compared to petroleum bitumen has been developed. The introduction of used polymer waste as a modifier does not require the installation of an additional homogenizer (colloidal mill), and there is no need to introduce a plasticizer to achieve the desired uniformity of the system and required by the Kazakhstan standard PMB 40 and PMB 90. Thanks to the use of this technological solution, it is possible to level the problem of disposal of household polymer waste with the polymer-bitumen binder production. This polymer modifier is characterized by low cost of its production. The advantage of the used polymer additive is the stage of polymer preparation - the process of joint chemical destruction of secondary polyethylene terephthalate in the presence of a highly elastic styrene-butadiene-styrene polymer to inhibit the delamination of polymer components in bitumen, due to which the problem of manufacturing high-quality homogenization of the product is solved.
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