This work describes the first thermally activated delayed fluorescence material enabling circularly polarized light emission through chiral perturbation. These new molecular architectures obtained through a scalable one-pot sequential synthetic procedure at room temperature (83% yield) display high quantum yield (up to 74%) and circularly polarized luminescence with an absolute luminescence dissymmetry factor, |glum|, of 1.3 × 10−3. These chiral molecules have been used as an emissive dopant in an organic light emitting diode exhibiting external quantum efficiency as high as 9.1%.

The design of fluorophores merging circularly polarized luminescence and thermally activated delayed fluorescence properties has recently emerged as a promising direction for the development of efficient CP‐Organic Light‐Emitting Diodes (CP‐OLEDs). This progress report gives an overview of the molecular designs explored to obtain CP‐TADF properties, of their performances as chiral emitters in CP‐OLEDs, and discusses future challenges for this burgeoning field of research.