Nanoreinforced polymers have gained popularity in the last decades since they exhibit enhanced properties (compared to pristine polymers) that are useful in a wide range of applications. Unfortunately, dispersion of nanoparticles (NPs) into polymeric matrices is a major problem since they tend to form agglomerates, limiting the improvement of properties and further applications. In this work, we propose the use of coaxial electrospinning as one-step method to disperse NPs in a polymeric matrix. Particularly, iron oxide (Fe 3 O 4) NP with a monomodal and bimodal size distributions were dispersed in polyvinylidene fluoride (PVDF), a material that is well known for its improved piezoelectric properties when it is processed via electrospinning. The results indicate that the incorporation of NP modified the polymeric fiber depending on their surface-to-volume ratio (smaller NP promoted smaller fiber size). Moreover, transmission electron microscopy revealed a good NP dispersion in the polymer, especially for the smallest NP size (monomodal). Finally, each NP size distributions were well preserved in the electrospun mats compared to the initial NP solutions, demonstrating the suitability of this technique for the fabrication of nanoreinforced PVDF structures with tailored NP size. Overall, this method could represent a facile and practical alternative to fabricate materials with piezoelectric/super-paramagnetic properties.
Abstract. The modeling and design of eddy currents sensors for non-destructive testing applications, generally, requires numerical methods. Among these methods, the finite element method is one of the most used. Indeed, it presents a great capability to treat a large variety of configurations. However, in the study of eddy current testing problems, the existence of structures that have a geometrical dimension smaller than the others (thin air gaps, coatings...) will lead to difficulties related to the meshing process. The introduction of particular elements such as shell elements allows to simplify the modeling of these problems. In this paper, the shell elements are used in two different 2D axisymmetric formulations, the electric formulation a * and the magnetic formulation t-φ in order to simulate the behaviour of the electromagnetic fields. The results obtained with the two formulations are compared with analytical solutions.PACS. 81.70.-q Methods of materials testing and analysis -07.05.Tp Computer modeling and simulation
Abstract-This paper deals with the thermal modeling and experimental validation of a large prismatic Li-ion battery. A lumped model representing the main thermal phenomena in the cell, in and outside the casing is proposed. Most of the parameters are determined analytically, using physical and geometrical properties. The heat capacity, the internal thermal resistance and interfacial thermal resistance between the cell and its cooling system are experimentally identified. The proposed model is validated with a precision of 1°C.
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