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This paper aimed at studying the effect of magnesium concentration in molten aluminum produced from beverage cans on the process of aluminothermic reduction of Mn2O3 particles obtained from the cathodes of discharged alkaline batteries. The experimental results were analyzed by using thermodynamic fundamentals and kinetic modeling, while the characterization of the reaction products obtained allowed the mechanism of the process to be described. It was found that the addition of magnesium improves the wettability of solid particles by molten aluminum, thus increasing the reaction and its subsequent incorporation into the molten aluminum solution of Mn released from the reduction reaction. This work was carried out using several initial magnesium concentrations; 1.0, 2.0, 3.0, and 4.0 wt %, under a constant temperature of 1073 K, a constant treatment time of 240 min, and a constant agitation speed of 200 rpm. The results show that the higher the initial magnesium concentration in the molten alloy, the higher the speed of the chemical reduction reaction of the Mn2O3 particles.

This paper presents and discusses a methodology implemented to study the process of the preparation of aluminium alloy foams using the alloy A-242, beginning from the recycling of secondary aluminium obtained from beverage cans. The foams are prepared by a melting process by adding 0.50 wt.% calcium to the A-242 aluminium alloy with the aim to change its viscosity in the molten state. To obtain the foam, titanium hydride is added in different concentrations (0.50 wt.%, 0.75 wt.%, and 1.00 wt.%) and at different temperatures (923, 948 K, and 973 K) while the foaming time is kept constant at 30 s. For a set of experimental parameter values, aluminium alloy foams with the average relative density of 0.12 were obtained and had an 88.22% average porosity. In this way, it is possible to state that the preparation of aluminium alloy foams A-242 processed from the recycling of cans is possible, with characteristics and properties similar to those obtained using commercial-purity metals.

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