Coagulants and flocculants are used almost at all drinking water supply facilities, wastewater treatment plants of municipal and industrial enterprises in Belarus and Ukraine to intensify and increase the efficiency of the processes of purification, clarification and discoloration of water and wastewater. Mainly as coagulants aluminum and iron salts are used, as flocculants - active silicic acid, starch, cellulose derivatives, polyacryloamide, etc. Sulfuric acid treatment of alumina-containing raw materials allows, in the course of one process, to obtain a mixture of active substances - salts of aluminum, iron, active SiO2. In this case, there is no need to separate the salt from suspended particles and colloidal silicic acid. The presence of suspended dispersed particles in the active substance, as well as colloidal silicic acid and its salts, enhances and accelerates coagulation. The resulting solution, along with aluminum sulfate, contains silicic acid, which acts as a flocculant in the process of water purification. In addition, the processed products also contain ferrous sulfate, in the presence of which a better coagulation result is achieved. Industrial tests of the coagulant-flocculant were carried out in order to purify wastewater from oil products. The test results showed that the effectiveness of the coagulant-flocculant in reducing the content of oil products in wastewater is comparable to the currently used aluminum sulfate. The effectiveness of the developed coagulant-flocculant for the purification of drinking water was evaluated in comparative tests with a coagulant “Polvak-68” in the mode of trial coagulation on a laboratory flocculator. The research results are showed that the value of all parameters characterizing the contamination of the source water are highty decreasing for experimental coagulant-flocculant in compare with regular product.
Inorganic sorbents are more selective in comparison with commercial ion exchange resins towards of metal ions. However, inorganic sorbents characterized not high kinetic properties. One of the way to increase the kinetic rate of inorganic sorbents is to reduce the particle size of these materials, other way is synthesizing inorganic sorbents as porous products from powder materials. A sample of such inorganic sorbents is titanium phosphate of various compositions. Studying the properties of microfilters based on composition titanium phosphate - porous titanium has been developed. The sorbents based on acidic titanium phosphate Ti(HPO4)2∙H2O were used for filtering solution with Fe(II) content. It is found that the number of impregnations with inorganic sorbent modificator is important and influence filtration process. The obtained results demonstrated that after the first impregnation of porous material with a smaller pore size, it is possible to obtain such sorbent as a mass content of powder material. By varying the ionic form of titanium phosphate, the porosity of titanium, the amount of impregnation, it could be possible effect on the sorption Fe(II). The sorption properties of titanium-titanium phosphate microfilters were studied by potentiometric titration in the NaCl-NaOH system, as well as the sorption of Fe2+ ions. The degree of purification for Fe(II) from solution with a concentration of 10 mg/l is 64 %. Application an electric potential to the microfilter of porous titanium - phosphate titanium increases the degree of purification of Fe(II) to 88 %.
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