In this paper, using the Optical Emission Spectroscopy technique, the physical properties of a fabricated pulsed DBD plasma jet are studied. Ar/N 2 gaseous mixture is taken as operational gas, and Ar contribution in Ar/N 2 mixture is varied from 75 to 95%. Through the optical emission spectra analysis of the pulsed DBD plasma jet, the rotational, vibrational and excitation temperatures and density of electrons in plasma medium of the pulsed plasma jet are obtained. It is seen that, at the wavelength of 750.38 nm, the radiation intensity from the Ar 4p ? 4 s transition increases at the higher Ar contributions in Ar/N 2 mixture. It is found that, for 95% of Ar presence in the mixture, the emission intensities from argon and molecular nitrogen are higher, and the emission line intensities will increase nonlinearly. In addition, it is observed that the quenching of Ar * by N 2 results in the higher intensities of N 2 excited molecules. Moreover, at the higher percentages of Ar in Ar/N 2 mixture, while all the plasma temperatures are increased, the plasma electron density is reduced.

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The applicability of high voltage electrical discharges for the decomposition of CO2 has been extensively demonstrated. In this study, a new AC parallel-plate plasma reactor is presented which was designed for this purpose. Detailed experimental characterization and simulation of this reactor were performed. Gas chromatography of the exhaust gases enabled calculation of the CO2 conversion and energy efficiency. A conversion factor approximating 25% was obtained which is higher in comparison to existing plasma sources. Optical emission spectroscopy enabled the determination of the emission intensities of atoms and molecules inside the plasma and characterization of the discharge. The Stark broadening of the Balmer hydrogen line Hβ was used for the estimation of the electron density. The obtained densities were of the order of 5 × 1014 cm−3 which indicates that the electron kinetic energy dominated the discharge. The rotational, vibrational, and excitation temperatures were determined from the vibro-rotational band of the OH radical. A 2-temperature plasma was found where the estimated electron temperatures (~18,000 K) were higher than the gas temperatures (~2000 K). Finally, a 2-D model using the fluid equations was developed for determining the main processes in the CO2 splitting. The solution to this model, using the finite element method, gave the temporal and spatial behaviors of the formed species densities, the electric potential, and the temperatures of electrons.

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In this paper, using the optical emission spectroscopy technique, a comparative study is performed on the argon excitation and nitrogen vibrational temperatures in the plasma discharge medium of a manufactured RF plasma jet. The argon contribution in the Ar/N 2 mixture is varied from 70% to 98% and the obtained optical emission spectra from argon and molecular nitrogen are analyzed. The highest emission intensities of neutral argon (Ar I) are recorded in the wavelength range of 790-850 nm. It is seen that, at the higher argon percentages in the mixture, the emission intensity from all the formed species in the plasma discharge medium of the RF plasma jet will increase. In addition, at the lower Ar contributions in the mixture, both the argon excitation and nitrogen vibrational temperatures are higher. Furthermore, it is shown that, at the higher Ar percentages in the mixture, both of the electronic temperatures are decreased.