Recently, adsorption process has been introduced as a favorable and effective technique for the removal of metal ions from aqueous solutions. In the present study, bimetallic nanoparticles consisting of zero valent iron and silver were loaded on the activated carbon powder for the preparation of a new adsorbent (PAC-Feo/Ag). The above adsorbent was characterized by using XRD, SEM and TEM techniqes. Experimental data were exploited for kinetic, equilibrium and thermodynamic evaluations related to the adsorption processes. The Cr(VI) adsorption process was found to be favorable at pH 3 and it reached equilibrium state within 60 min. The stirring rate did not have a significant effect on the adsorption efficiency. Furthermore, the monolayer adsorption capacity of Cr(VI) based on the Langmuir model was measured to be 100 mg/g. The experimental equilibrium data were fitted to the Freundlich adsorption and pseudo second-order models. According to the thermodynamic study, the adsorption process was spontaneous and endothermic in nature, indicating the adsorption capacity increases with increasing the temperature. The results also revealed that the synthesized composite can be potentially applied as a magnetic adsorbent to remove Cr(VI) contaminants from aqueous solutions.

In recent decades, climate change has been of great concern due to its effect on water level and its impact on aquatic ecosystems. Urmia Lake, the largest inland wetland in Iran, has been shrinking. There is a great concern whether it will dry up like the Aral Sea. Therefore, a hydrodynamic model has been developed to simulate the condition of Urmia Lake. The model has been validated using the known annual data on precipitation, evaporation, run off, river discharges and water level which are available for the last 35 years. Different hydrological conditions regarding lake input and output data were tested and water depth was calculated using bathymetry to predict waterlevel fluctuations in the future. The results predict that the water level will decrease continuously. The lake will be dried up in about 10 years if very dry conditions continue in the region. The drought speed cannot be reduced and there is no potential to develop a water-usage program. Besides, the lake water depth decrease is more slightly, applying alternate wet and dry-period conditions. In some hydrological conditions there is a good potential to consider water development projects. The sensitivity analysis of different parameters indicates that the lake is highly sensitive to river discharges, which implies that the water development project plans will disturb the lake ecosystem if implemented up to 2021 and integrated watershed management plan for the lake can change the condition by regulating the dam output.

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The Persian Gulf is one of the aquatic ecosystems which has recently faced with different pollutions. Cooling water discharges due to various industries such as power plants can cause important disorders on present ecosystem balance because of its high temperature. Obviously, due to thermal pollution, a great number of aquatic creatures face with a new situation that they can not tolerate. Thermal pollution leads to their migration, creates a potential for new coming species which in turn can thoroughly change the marine ecosystem feature. The other impacts of this phenomenon are: disorders in reproduction, nourishment and other biological habits. In this research, thermal pollution due to Bandar Abbas Thermal Power Plant (BATP) development plan was modeled using MIKE21 software. In order to avoid a decrease on the power plant efficiency in development plan, the distance between inlet and outlet was determined by comparing the results of different scenarios and economical aspects. After determining the distance between inlet and outlet, the water temperature in the coastal area was compared with standards of Iranian Department of the Environment (DOE). The model results represent that the water temperature, in Bandar Abbas coastal area, exceeds than the permissible limit (3 o C) in a distance equal to 200 m. far from the discharging location, and in order to reduce its harmful impacts, some suggestions are made to reduce the associated thermal pollution.

Abstract.A three dimensional numerical model namely POM (Princeton Ocean Model) and observational data are used to study the Persian Gulf outflow structure and its spreading pathways during 1992. In the model, the monthly wind speed data were taken from ICOADS (International Comprehensive Ocean-Atmosphere Data Set) and the monthly SST (sea surface temperatures) were taken from AVHRR (Advanced Very High Resolution Radiometer) with the addition of monthly net shortwave radiations from NCEP (National Center for Environmental Prediction). The mean monthly precipitation rates from NCEP data and the calculated evaporation rates are used to impose the surface salinity fluxes. At the open boundaries the temperature and salinity were prescribed from the mean monthly climatological values from WOA05 (World Ocean Atlas 2005). Also the four major components of the tide were prescribed at the open boundaries. The results show that the outflow mainly originates from two branches at different depths in the Persian Gulf. The permanent branch exists during the whole year deeper than 40m along the Gulf axis and originates from the inner parts of the Persian Gulf. The other seasonal branch forms in the vicinity of the shallow southern coasts due to high evaporation rates during winter. Near the Strait of Hormuz the two branches join and form the main outflow source water. The results of simulations reveal that during the winter the outflow boundary current mainly detaches from the coast well before Ras Al Hamra Cape, however during summer the outflow seems to follow the coast even after this Cape. This is due to a higher density of the colder outflow that leads to more sinking near the coast in winter. Thus, the outflow moves to a deeper depth of about 500 m (for which Correspondence to: M. Ezam (ezam@srbiau.ac.ir) some explanations are given) while the main part detaches and spreads at a depth of about 300 m. However in summer it all moves at a depth of about 200-250 m. During winter, the deeper, stronger and wider outflow is more affected by the steep topography, leading to separation from the coast. While during summer, the weaker and shallower outflow is less influenced by bottom topography and so continues along the boundary.