Black phosphorus is a two-dimensional material of great interest, in part because of its high carrier mobility and thickness dependent direct bandgap. However, its instability under ambient conditions limits material deposition options for device fabrication. Here we show a black phosphorus ink that can be reliably inkjet printed, enabling scalable development of optoelectronic and photonic devices. Our binder-free ink suppresses coffee ring formation through induced recirculating Marangoni flow, and supports excellent consistency (< 2% variation) and spatial uniformity (< 3.4% variation), without substrate pre-treatment. Due to rapid ink drying (< 10 s at < 60 °C), printing causes minimal oxidation. Following encapsulation, the printed black phosphorus is stable against long-term (> 30 days) oxidation. We demonstrate printed black phosphorus as a passive switch for ultrafast lasers, stable against intense irradiation, and as a visible to near-infrared photodetector with high responsivities. Our work highlights the promise of this material as a functional ink platform for printed devices.
We present a self-powered, high-performance graphene-enhanced ultraviolet silicon Schottky photodetector. Different from traditional transparent electrodes, such as indium tin oxides or ultra-thin metals, the unique ultraviolet absorption property of graphene leads to long carrier life time of hot electrons that can contribute to the photocurrent or potential carrier-multiplication. Our proposed structure boosts the internal quantum efficiency over 100%, approaching the upper-limit of silicon-based ultraviolet photodetector. In the near-ultraviolet and mid-ultraviolet spectral region, the proposed ultraviolet photodetector exhibits high performance at zero-biasing (self-powered) mode, including high photo-responsivity (0.2 A W −1 ), fast time response (5 ns), high specific detectivity (1.6 × 10 13 Jones), and internal quantum efficiency greater than 100%. Further, the photo-responsivity is larger than 0.14 A W −1 in wavelength range from 200 to 400 nm, comparable to that of state-of-the-art Si, GaN, SiC Schottky photodetectors. The photodetectors exhibit stable operations in the ambient condition even 2 years after fabrication, showing great potential in practical applications, such as wearable devices, communication, and "dissipation-less" remote sensor networks.
High-performance photodetectors operating over a broad wavelength range from ultraviolet, visible, to infrared are of scientific and technological importance for a wide range of applications. Here, a photodetector based on van der Waals heterostructures of graphene and its fluorine-functionalized derivative is presented. It consistently shows broadband photoresponse from the ultraviolet (255 nm) to the mid-infrared (4.3 µm) wavelengths, with three orders of magnitude enhanced responsivity compared to pristine graphene photodetectors. The broadband photodetection is attributed to the synergistic effects of the spatial nonuniform collective quantum confinement of sp domains, and the trapping of photoexcited charge carriers in the localized states in sp domains. Tunable photoresponse is achieved by controlling the nature of sp sites and the size and fraction of sp /sp domains. In addition, the photoresponse due to the different photoexcited-charge-carrier trapping times in sp and sp nanodomains is determined. The proposed scheme paves the way toward implementing high-performance broadband graphene-based photodetectors.
A significant growth in solar photovoltaic (PV) installation has observed during the last decade in standalone and grid-connected power generation systems. The solar PV system has a non-linear output characteristic because of weather intermittency, which tends to have a substantial effect on overall PV system output. Hence, to optimize the output of a PV system, different maximum power point tracking (MPPT) techniques have been used. But, the confusion lies while selecting an appropriate MPPT, as every method has its own merits and demerits. Therefore, a proper review of these techniques is essential. A "Google Scholar" survey of the last five years (2015-2020) was conducted. It has found that overall seventy-one review articles are published on different MPPT techniques; out of those seventy-one, only four are on uniform solar irradiance, seven on non-uniform and none on hybrid optimization MPPT techniques. Most of them have discussed the limited number of MPPT techniques, and none of them has discussed the online and offline under uniform and hybrid MPPT techniques under non-uniform solar irradiance conditions all together in one. Unfortunately, very few attempts have made in this regard. Therefore, a comprehensive review paper on this topic is need of time, in which almost all the well-known MPPT techniques should be encapsulated in one paper. This article focuses on classifications of online, offline, and hybrid optimization MPPT algorithms, under the uniform and non-uniform irradiance conditions. It summarizes various MPPT methods along with their mathematical expression, operating principle, and block diagram/flow charts. This research will provide a valuable pathway to researchers, energy engineers, and strategists for future research and implementation in the field of maximum power point tracking optimization.
Continuously increasing demand of microgrids with high penetration of distributed energy generators, mainly renewable energy sources, is modifying the traditional structure of the electric distribution grid. Major power consumer countries are looking for alternative energy sources to avoid the impact of higher fossil fuel consumption. Thus, different policies have been promulgated to promote renewable energy technologies (RETs) and distributed energy resource (DER) deployment and are encouraging technological innovation. These policies aim to reduce greenhouse gas (GHG) emissions and achieve energy security and independence to meet an ever-increasing electricity demand. Many studies have been performed on the successful integration of RET and DER operation and control, protection and stability issues, all simultaneously and satisfactorily implemented during feasible microgrid operation. However, apart from the technical challenges, few microgrid studies exist on effective policies and incentives for microgrid promotion and deployment. This survey investigates the policy, regulatory and financial (economical and commercial) barriers, which hinder the deployment of microgrids in the European Union (EU), United States (USA) and China. In this paper, a clear view on microgrid policy instruments and challenges are investigated to aid future developments.
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