High‐resolution seismic profiles acquired in the eastern sector of Lago Fagnano, the southernmost ice‐free lake in the world, have shown the presence of very shallow gas‐bearing layers in the upper sedimentary sequences. The gas‐related features observed on seismic profiles include a typical, very strong reflection with reversed polarity, multiple reflections and acoustic blanking that hide subsurface sedimentary and structural features. The top of the acoustically high‐amplitude layer is located between 0.3–1.7 m below the lake floor. It generally forms a sharp boundary, often marked by a varying offset probably due to different levels of gas penetration, which could be related to the lithology of the overlying sediments. To confirm the presence of gas, some gravity cores were recovered in places where the blanking effect was most relevant and in the supposed gas‐free zone. Sediment core analyses have highlighted the occurrence of significant organic‐rich components within the uppermost, largely unconsolidated sedimentary layers, in correspondence of the seismically‐detected gassy zone, whereas only a few organic layers were found in the gas‐free zone. We assume that the main origin of gas is linked to the presence of a shallow, thin peat‐rich layer of Middle‐Late Holocene age. In fact, the mapped gassy zone occurs in correspondence of the outlet of the Rio Turbio, the principal tributary of Lago Fagnano, which discharges waters coming from a relatively small sag pond located immediately to the east of the eastern shore of the lake. To date, this is the first evidence of shallow gas in Tierra del Fuego lakes.
Groundwater remediation operation involves several considerations in terms of environmental, technological and socio-economic aspects. A decision support tool (DST) becomes therefore necessary in order to manage problem complexity and to define effective groundwater remediation interventions. CCR (Credence Clearwater Revival), a decision support tool for groundwater remediation technologies assessment and selection, has been developed to help decision-makers (site owners, investors, local community representatives, environmentalists, regulators, etc.) to assess the available technologies and select the preferred remedial options. The analysis is based on technical, economical, environmental and social criteria. These criteria are ranked by all involved parties to determine their relative importance for a particular groundwater remediation project. The Multi-Criteria Decision Making (MCDM) is the core of the CCR using the PROMETHEE II algorithm.
Triplet state traps, observed on optically excited single crystals of Naphthalene-TCNB doped with Pyrene, have been studied by EPR and ENDOR spectroscopy. The magnetic resonance lines recorded at low temperature (20 K) are shown to be due to triplet excitations localized almost completely on a Pyrene molecule. The complete hyperfine tensors of all the protons have been determined. The spin distribution is shown to be distorted in such a way that the triplet Pyrene molecule lacks the in-plane symmetry axes of the ground state molecule. The orientation of the triplet molecule in the crystal lattice and the relative orientation of Pyrene and TCNB are also discussed.
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