The conversion of diverse polymeric substrates into laser-induced graphene (LIG) has recently emerged as a single-step method for the fabrication of patterned graphene-based wearable electronics with a wide range of applications in sensing, actuation, and energy storage. Laser-induced pyrolysis technology has many advantages over traditional graphene design: eco-friendly, designable patterning, roll-to-roll production, and controllable morphology. In this work, we designed wearable and flexible graphenebased strain and pressure sensors by laminating LIG from a commercial polyimide (PI) film. The as-prepared LIG was transferred onto a thin polydimethylsiloxane (PDMS) sheet, interwoven inside an elastic cotton sports fabric with the fabric glue as a wearable sensor. The single LIG/PDMS layer acts as a strain sensor, and a two-layer perpendicular stacking of LIG/PDMS (x and y laser-directed films) is designed for pressure sensing. This newly designed graphene textile (IGT) sensor performs four functions in volleyball sportswear, including volleyball reception detection, finger touch foul detection during blocking the ball from an opponent player, spike force measurements, and player position monitoring. An inexpensive sensor assists athletes in training and helps the coach formulate competition strategies.

Organic pollutants (OPs) have garnered a considerable amount of attention in recent times due to their extreme toxicity toward humans and the ecosystem. The need for an inexpensive yet robust, sensitive, selective, and easy-to-operate method for detecting OPs remains a challenge. Herein, a portable electrochemical sensor is proposed based on manganese porphyrin-functionalized carbon cloth (CC). To explain the electrochemical performance of the sensor, cyclic voltammetry (CV) and differential pulse voltammetry (DPV) were employed. The presence of manganese(III) ion in the center of the porphyrin ligand acted as an agent for the transfer of electrons and enhanced sensitivity toward analytespecific redox catalysis. Moreover, it allowed for the concurrent detection of multiple analytes in a complex environment. The modified CC electrode can selectively detect nitroaromatic and phenolic compounds with accessible data collected through wireless means onto a smartphone device. The as-synthesized electrode demonstrated a higher sensitivity toward the detection of nitrobenzene (NB) and aqueous phenol with a limit of detection (LOD) found to be 5.9268 × 10 −10 M and 4.0178 × 10 −10 M, respectively. Additionally, our proposed portable electrochemical sensor demonstrates a high selectivity and reproducibility toward nitroaromatic and phenolic compounds, which can be employed in real complex water samples. With regard to the sensor's remarkable electrochemical performance, it is envisaged that such a sensor could pave the way for environmental point of care (POC) testing.

In the face of complex environments, considerable effort has been made to accomplish sensitive, accurate and highly-effective detection of target analytes. Given the versatility of metal clusters and ligands, high porosity and large specific surface area, metal–organic framework (MOF) provides researchers with prospective solutions for the construction of biosensing platforms. Combined with the benefits of electrochemistry method such as fast response, low cost and simple operation, the untapped applications of MOF for biosensors are worthy to be exploited. Therefore, this review briefly summarizes the preparation methods of electroactive MOF, including synthesize with electroactive ligands/metal ions, functionalization of MOF with biomolecules and modification for MOF composites. Moreover, recent biosensing applications are highlighted in terms of small biomolecules, biomacromolecules, and pathogenic cells. We conclude with a discussion of future challenges and prospects in the field. It aims to offer researchers inspiration to address the issues appropriately in further investigations.