Forward osmosis (FO) is a membrane technology that uses the osmotic pressure difference to treat two fluids at a time giving the opportunity for an energy-efficient water and wastewater treatment. Various applications are possible; one of them is the application in industrial water management. In this review paper, the basic principle of FO is explained and the state-of-the-art regarding FO application in manufacturing industries is described. Examples of FO application were found for food and beverage industry, chemical industry, pharmaceutical industry, coal processing, micro algae cultivation, textile industry, pulp and paper industry, electronic industry, and car manufacturing. FO publications were also found about heavy metal elimination and cooling water treatment. However, so far FO was applied in lab-scale experiments only. The up-scaling on pilot- or full-scale will be the essential next step. Long-term fouling behavior, membrane cleaning methods, and operation procedures are essential points that need to be further investigated. Moreover, energetic and economic evaluations need to be performed before full-scale FO can be implemented in industries.
Forward osmosis (FO) is a potential membrane technology to treat wastewater energy efficiently with low fouling. In laboratory-scale experiments, six effluents from a dairy and an automobile production plant were tested to find out if FO is an applicable treatment technology. Permeate flux and reverse salt flux were determined in nine test series with three subsequent 5 h experiments each. In between, the membrane was cleaned with deionized water. Membrane performance tests before each experiment were used to monitor membrane performance and fouling. Samples were analysed and the T/M-value was introduced to indicate which substances caused fouling. Dairy cheese brine was a suitable DS. Here, permeate fluxes were 21.0 and 15.1 L/(m²·h). Automobile cooling tower water and wastewater from cathodic dip painting were also used as DS. However, permeate fluxes were below 1.1 L/(m²·h). The tested FS, reverse osmosis concentrate from dairy wastewater treatment, rinsing water and wastewater from automobile cathodic dip painting, as well as wastewater from automobile paint shop pre-treatment, showed good performance regarding the permeate flux of between 7.9 and 19.4 L/(m²·h). Membrane performance test showed that some of the effluents lead to permeate flux reduction due to fouling. Different cleaning-in-place methods were examined. Eventually, permeate flux was restored.
Forward osmosis (FO) has rarely been investigated as a treatment technology for industrial wastewaters. Within this study, common FO model equations were applied to simulate forward osmosis treatment of industrial wastewaters from the automobile industry. Three different models from literature were used and compared. Permeate and reverse solute flux modelling was implemented using MS Excel with a Generalized Reduced Gradient (GRG) Nonlinear Solver. For the industrial effluents, the unknown diffusion coefficients were calibrated and the influences of the membrane parameters were investigated. Experimental data was used to evaluate the models. It could be proven that common model equations can describe FO treatment of industrial effluents from the automobile industry. Even with few known solution properties, it was possible to determine permeate fluxes and draw conclusions about mass transport. However, the membrane parameters, which are apparently not solution independent and seem to differ for each industrial effluent, are critical values. Fouling was not included in the model equations although it is a crucial point in FO treatment of industrial wastewaters. But precisely for this reason, modelling is a good complement to laboratory experiments since the difference between the results allows conclusions to be drawn about fouling.
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