Synthetic slag samples of the CaO-SiO2-MgO-Al2O3-Cr2O3 system were obtained to clarify the effect of FeO on the formation of spinel phases and Cr distribution. X-ray diffraction (XRD) and scanning electron microscopy (SEM) equipped with energy-dispersive spectroscopy (EDS), as well as the thermodynamic software FactSage 6.2, were used for sample characterization. The results show that the addition of FeO can decrease the viscosity of molten slag and the precipitation temperatures of melilite and merwinite. The solidus temperature significantly decreases from 1400 to 1250• C with the increase of FeO content from 0wt% to 6wt%. The addition of FeO could enhance the content of Cr in spinel phases and reduce the content of Cr in soluble minerals, such as merwinite, melilite, and dicalcium silicate. Hence, the addition of FeO is conducive to decreasing Cr leaching.

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High CO2 emissions and energy consumption have greatly restricted the development of China’s iron and steel industry. Two alternative ironmaking processes, top gas recycling-oxygen blast furnace (TGR-OBF) and COREX®, can reduce CO2 emissions and coking coal consumption in the steel industry when compared with a conventional blast furnace (BF). To obtain parameters on the material flow of these processes, two static process models for TGR-OBF and COREX were established. Combining the operating data from the Jingtang steel plant with established static process models, this research presents a detailed analysis of the material flows, metallurgical gas generation and consumption, electricity consumption and generation, comprehensive energy consumption, and CO2 emissions of three integrated steel plants (ISP) equipped with the BF, TGR-OBF, and COREX, respectively. The results indicated that the energy consumption of an ISP with the TGR-OBF was 16% and 16.5% lower than that of a conventional ISP and an ISP with the COREX. Compared with a conventional ISP, the coking coal consumption in an ISP with the TGR-OBF and an ISP with the COREX were reduced by 39.7% and 100% respectively. With the International Energy Agency factor, the ISP with the TGR-OBF had the lowest net CO2 emissions, which were 10.8% and 35.0% lower than that of a conventional ISP and an ISP with the COREX. With the China Grid factor, the conventional ISP had the lowest net CO2 emissions—2.8% and 24.1% lower than that of an ISP with the TGR-OBF and an ISP with the COREX, respectively.

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