Highlights US-assisted photocatalysis by ZnO leads to efficient mineralization of diclofenac. Synergistic effects are observed only when ZnO nanorods are used. Tests in simulated water matrix show enhanced performance with respect to TiO 2 . Reaction intermediates of photo- and sonophotocatalysis are identified.

In the present study, the development of innovative polyurethane-polyaniline/TiO2 modified floating materials applied in the sorption and photodegradation of rhodamine B from water matrix under solar light irradiation is reported. All the materials were fabricated with inexpensive and easy approaches and were properly characterized. The effect of the kind of polyaniline (PANI) dopant on the materials’ behavior was investigated, as well as the role of the conducting polymer in the pollutant abatement on the basis of its physico-chemical characteristics. Rhodamine B is removed by adsorption and/or photodegradation processes depending on the type of doping agent used for PANI protonation. The best materials were subjected to recycle tests in order to demonstrate their stability under the reaction conditions. The main transformation products formed during the photodegradation process were identified by ultraperformance liquid chromatography-mass spectrometry (UPLC/MS). The results demonstrated that photoactive floating PANI/TiO2 composites are useful alternatives to common powder photocatalysts for the degradation of cationic dyes.

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Flood mitigation measures delivered at the London 2012 Olympic Park have reduced flood risk to more than 4000 residential and commercial properties, improving the quality of life for thousands of east London residents. Additional benefits include water quality, habitat creation, biodiversity, recreation, leisure and education. This was achieved by adopting a collaborative approach across a team that included contractors, planners and key stakeholders. The result is a true and lasting legacy for London and a model for sustainable flood risk management.