Cerium molybdenum oxide hydrate microflakes are codeposited with nickel from a deep eutectic solvent-based bath. During seven days of exposure in 0.05 M NaCl solution, the corrosion resistance of composite coating (Ni/CeMoOxide) is slightly reduced, due to the existence of some microcracks caused by large microflakes. Multielemental analysis of the solution, in which coatings are exposed and the qualitative changes in the surface chemistry (XPS) show selective etching molybdenum from microflakes. The amount of various molybdenum species within the surface of coating nearly completely disappear, due to the corrosion process. Significant amounts of Ce3+ compounds are removed, however the corrosion process is less selective towards the cerium, and the overall cerium chemistry remains unchanged. Initially, blank Ni coatings are covered by NiO and Ni(OH)2 in an atomic ratio of 1:2. After exposure, the amount of Ni(OH)2 increases in relation to NiO (ratio 1:3). For the composite coating, the atomic ratios of both forms of nickel vary from 1:0.8 to 1:1.3. Despite achieving lower corrosion resistance of the composite coating, the applied concept of using micro-flakes, whose skeleton is a system of Ce(III) species and active form are molybdate ions, may be interesting for applications in materials with potential self-healing properties.

Ni–Mo alloy coatings were deposited on a copper base material from a non-aqueous plating bath based on a deep eutectic solvent (DES) of choline chloride and propylene glycol in a 1:2 molar ratio containing 0.2 mol dm−3 NiCl2 · 6H2O and 0.01 mol dm−3 (NH4)6Mo7O24·4H2O. Uniform and adherent Ni–Mo deposits with a nodular morphology were obtained at all the deposition potentials investigated (from − 0.5 to − 0.9 V vs. Ag). By shifting the potential from − 0.5 to − 0.9 V, the deposition current density increased from − 0.4 to − 1.5 mA cm−2 and the overall surface roughness increased. It was also accompanied by an increase in the Mo content from ~ 7 to ~ 13 wt% in the potential range from − 0.5 to − 0.7 V. A further change in the potential from − 0.8 to − 0.9 V caused a decrease in the Mo content to ~ 10 wt% and a deterioration in the quality of the coating. For the most uniform coating, deposited at − 0.6 V and having a thickness of ca. 660 nm, the crystallite size did not exceed 10 nm. With the content of Ni (89 at.%) and Mo (11 at.%), the selected area electron diffraction (SAED) analysis allowed us to identify the cubic phase Ni3.64Mo0.36. The corrosion resistance of Ni–Mo coatings in 0.05 mol dm−3 NaCl solution generally increased during exposure of 18 h, as evidenced by ever higher polarization resistance. Finally, regardless of the applied deposition potential, low corrosion currents (in the range of 0.1–0.3 μA cm−2) have been measured for the coatings. EIS revealed that charge transfer resistances were the highest (57–67 kΩ cm2) for coatings deposited at − 0.5 V, − 0.6 V and − 0.7 V. Further increase in the deposition potential in the negative direction was unfavorable.

Fabrication of nanometric color TiO2 layers through polarization of titanium in a choline dihydrogencitrate–oxalic acid DES anodizing bath.