Titanium anodizing in a choline dihydrogencitrate salt–oxalic acid deep eutectic solvent: a step towards green chemistry in surface finishing of titanium and its alloys

Winiarski, J.; Niciejewska, Anna; Górnik, Monika; Jakubowski, Jakub; Szczygieł, B.

doi:10.1039/d1ra01655e

Cited by 12 publications

(2 citation statements)

References 31 publications

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“…A separate method was presented by Chen et al who, using choline chloride and succinic acid (1:1), applied anodic dissolution to titanium and obtained titanium oxide nanoparticles [ 87 ]. After the application of a choline dihydrogencitrate salt–oxalic acid, titanium oxide nanoparticles were also obtained, but with a different structure [ 88 ].…”

Section: Natural Deep Eutectic Solvents Applications In Nanotechnologymentioning

confidence: 99%

Natural Deep Eutectic Solvents in the Synthesis of Inorganic Nanoparticles

Długosz

2023

Materials

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Natural deep eutectic solvents (NDESs), as a new type of green solvent, are used in many fields, including industry in extraction processes, medicine, pharmaceuticals, metallurgy, electrodeposition, separations, gas capture, biocatalysis and nanotechnology. Mainly due to their properties, such as simple preparation, environmental friendliness, biocompatibility and multifunctionality, they are being used in various fields of industry. This review aims to provide insight into the applications of natural deep eutectic solvents, specifically in nanotechnology processes. It focuses on the description of NDES and how their physicochemical properties are used to obtain functional nanomaterials, including metals, metal oxides and salts. It highlights how the use of NDESs to obtain a wide range of inorganic nanoparticles enables the elimination of disadvantages of traditional methods of obtaining them, including reducing energy consumption and functionalising nanoparticles in situ. In conclusion, recent advances and future directions in the development and applications of NDESs in nanotechnology are discussed with the aim of identifying unexplained scientific questions that can be investigated in the future.

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Section: Natural Deep Eutectic Solvents Applications In Nanotechnologymentioning

confidence: 99%

Natural Deep Eutectic Solvents in the Synthesis of Inorganic Nanoparticles

Długosz

2023

Materials

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“…Ellipsometry measurements of the electrode showed a decrease in the thickness of the native oxides from 48.4 AE 0.4 nm before electrolysis to 17.9 AE 1.5 nm after electrolysis, as depicted in Table S2 (ESI †). The reduction in the thickness of the native oxides of titanium after electrolysis could be due to the etching of the oxides by the acid, 39,40 or else to the reduction of part of the oxide to the metal during electrolysis. The electrode's ellipsometry fitting model is represented in Fig.…”

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confidence: 99%