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The aqueous geochemistry of the sand‐and‐gravel aquifer in northwest Florida was characterized as part of the Florida Ground‐Water Quality Monitoring Network Program, a multiagency cooperative study delineating baseline and/or background water quality for the major aquifer systems throughout the State. The aquifer is the principal source of water in northwest Florida and consists predominantly of quartz sand with smaller amounts of andesine, chlorite, calcite, kaolinite, and illite. Water from 42 wells in the sand‐and‐gravel aquifer sampled during 1986 and 1987 was characteristically low in dissolved solids (median value of 72 milligrams per liter) and of nondistinct water type, although relative concentrations of magnesium and sulfate tended to be lower than those of other major ions. Nonparametric statistical tests of major‐ion concentration variations with depth and relative distance along flow paths indicate that the water chemistry does not change significantly (0.05 significance level) as the water moves vertically and laterally through the aquifer. Mass‐balance calculations indicate that dissolved solids from rainfall and saline‐water sources each account for 13 percent of the concentration of dissolved solids in ground water. Incongruent dissolution of andesine, chlorite, and muscovite to form kaolinite accounts for 94 percent of the neutralization of the total hydrogen ion input from rainfall and from carbonic acid weathering in the subsurface. The remaining neutralization is accounted for by the dissolution of calcite.