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The electrical and dielectric properties of liquids can be used for sensing. Specific applications, e.g., the continuous in-line monitoring of blood conductivity as a measure of the sodium concentration during dialysis treatment, require contactless measuring methods to avoid any contamination of the medium. The differential transformer is one promising approach for such applications, since its principle is based on a contactless, magnetically induced conductivity measurement. The objective of this work is to investigate the impact of the geometric parameters of the sample or medium under test on the sensitivity and the noise of the differential transformer to derive design rules for an optimized setup. By fundamental investigations, an equation for the field penetration depth of a differential transformer is derived. Furthermore, it is found that increasing height and radius of the medium is accompanied by an enhancement in sensitivity and precision.

In this work, we present a tandem ion mobility spectrometer (IMS) utilizing a highly efficient ion manipulator allowing to store, manipulate, and analyze ions under high electric field strengths and controlled ion-neutral reactions at ambient conditions. The arrangement of tandem drift regions and an ion manipulator in a single drift tube allows a sequence of mobility selection of precursor ions, followed by storage and analysis, mobility separation, and detection of the resulting product ions. In this article, we present a journey exploring the capabilities of the present instrument by a study of eight different primary alcohols characterized at reduced electric field strengths E/N of up to 120 Td with a water vapor concentration ranging from 40 to 540 ppb. Under these conditions, protonated alcohol monomers up to a carbon number of nine could be dissociated, resulting in 18 different fragmented product ions in total. The fragmentation patterns revealed regularities, which can be used for assignment to the chemical class and improved classification of unknown substances. Furthermore, both the time spent in high electrical field strengths and the reaction time with water vapor can be tuned precisely, allowing the fragment distribution to be influenced. Thus, further information regarding the relations of the product ions can be gathered in a standalone drift tube IMS for the first time.

Resistive voltage dividers tend to have a highly non-linear transfer function as parasitic and stray capacitances exert an increasing influence with increasing frequency. The non-linear transfer function depends on the topology and resistors used and consists of a low-pass filter with an additional high-pass component in the GHz range. Due to the non-linear transfer function the measured signal differs from the original input signal. Here, we present an improved resistive voltage divider with additional compensation capacities to extend the linear bandwidth. With this new concept, the linear bandwidth is improved from 115 kHz to 88 MHz, while maintaining a DC input impedance of 10 MΩ. For high-voltage insulation and easy manufacturing, surface mounted resistors on a printed circuit board with a compensation electrode on the adjacent side are used. The performance of this resistive voltage divider is demonstrated by measuring a series of high-voltage pulses with an amplitude of 2.5 kVpeak-peak. The measured pulse rise time is about 16 ns, corresponding to an average slew-rate of 150 V/ns. Finally, the developed resistive voltage divider is successfully used to measure fast high-voltage transients required for advanced ion mobility spectrometers with integrated collision induced fragmentation.

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