Aqueous solutions of polyvinyl alcohol (PVA) were electrospun and its characteristics were studied as a function of applied potential, tip-target distance and solution flow rate. Solutions of PVA and chitosan were homogeneously mixed and electrospun to result in blend nanofibres and their properties were investigated. Conditions were revealed under which multiscale bi-modal fibres could be electrospun in a single step, producing structures that have potential applications in tissue engineering. Electrospun fibres having a bimodal size distribution of poly(caprolactone) (PCL) were also fabricated using a modified electrospinning setup. Nanofibrous microporous PVA scaffolds were fabricated using a cryogenic grinding method with subsequent compaction. Such multiscale porous structures would offer ideal matrices for tissue engineering applications.
Cyanate
esters (CEs) are recognized as matrix materials in composites
for high-temperature structural applications, owing to their excellent
thermal and dimensional stability, resistance to micro-cracks, low
moisture absorption, and low dielectric loss. Though the brittle nature
of CEs curtails their effective utilization, thermoplastic toughening
has paved the way to circumvent their innate brittle attribute by
virtue of the resulting two-phase morphology. This Review enumerates
detailed deliberation on thermoplastic toughening of CEs and their
semi-interpenetrating networks. Further, the effects of various decisive
variables like thermoplastic concentration, molecular weight, and
curing conditions are also reviewed and disserted in detail. In addition,
the mechanical properties of numerous developed CE blends and their
toughening mechanism are deliberated to elucidate their substantial
engineering applications. This Review renders a detailed contemplation
on thermoplastic toughening of CEs, composite fabrication methodology,
and their structural integrity for high-temperature applications.
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