Biopolymers are materials synthesised or derived from natural sources, such as plants, animals, microorganisms or any other living organism. The use of these polymers has grown significantly in recent years as industry shifts away from unsustainable fossil fuel resources and looks towards a softer and more sustainable environmental approach. This review article covers the main classes of biopolymers: Polysaccharides, proteins, microbial-derived and lignin. In addition, an overview of the leading biomedical applications of biopolymers is also provided, which includes tissue engineering, medical implants, wound dressings, and the delivery of bioactive molecules. The future clinical applications of biopolymers are vast, due to their inherent biocompatibility, biodegradability and low immunogenicity. All properties which their synthetic counterparts do not share.
Gas-permeable membranes coupled with low-rate aeration is useful to recover ammonia (NH) from livestock effluents. In this study, the role of inorganic carbon (bicarbonate, HCO) to enhance the N recovery process was evaluated using synthetic effluents with various NH to HCO molar ratios of 0.5, 1.0, 1.5 and 2.0. The study also evaluated the effect of increased organic matter on the NH recovery using humic acids (3000-6000 mg L), and the N recovery from high-strength swine manure. The release of hydroxide from the HCO with aeration increased the wastewater pH and promoted gaseous ammonia formation and membrane uptake. At the same time, the recovery of gaseous ammonia (NH) through the membrane acidified the wastewater. Therefore, an abundant inorganic carbon supply in balance with the NH is needed for a successful operation of the technology. NH removal efficiencies >96% were obtained with NH to HCO ratios ≤1. However, higher molar ratios inhibited the N recovery process resulting in lower efficiencies (<65%). Fortunately, most swine manures contain ample supply of endogenous inorganic carbon and the process can be used to more economically recover the ammonia using the natural inorganic carbon instead of expensive alkali chemicals. In 4 days, the recovered NH from swine manure contained 48,000 mg L. Finally, it was found the process was not inhibited by the increasing levels of organic matter in the wastewater evaluated.
Olea europaea L. leaves constitute a source of bioactive compounds with recognized benefits for both human health and technological purposes. In the present work, different extracts from olive leaves were obtained by the application of two extraction methods, Soxhlet and microwave-assisted extraction (MAE), and six solvents (distilled water, ethanolic and glycerol mixtures solvents). MAE was applied under 40, 60 and 80 °C for 3, 6.5 and 10 min. The effect of the extraction method, solvent and treatment factors (the latter in MAE) on the total phenol content (TPC), the antioxidant activity (AA) and the phenolic profile of the extracts were all evaluated. The extracts showed high values of TPC (up to 76.1 mg GAE/g DW) and AA (up to 78 mg TE/g DW), with oleuropein being the most predominant compound in all extracts. The Soxhlet extraction method exhibited better yields in TPC than in MAE, although both methods presented comparable AA values. The water MAE extract presented the strongest antimicrobial activity against five foodborne pathogens, with minimum inhibitory concentration (MIC) values ranging from 2.5 to 60 mg/mL. MAE water extract is proposed to be exploited in the food and nutraceutical industry in the frame of a sustainable economy.
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