The proliferation of e-commerce sites and online social media has allowed users to provide preference feedback and maintain profiles in multiple systems, reflecting a variety of their tastes and interests. Leveraging all the user preferences available in several systems or domains may be beneficial for generating more encompassing user models and better recommendations, e.g., through mitigating the cold-start and sparsity problems in a target domain, or enabling personalized crossselling recommendations for items from multiple domains. Cross-domain recommender systems, thus, aim to generate or enhance recommendations in a target domain by exploiting knowledge from source domains. In this chapter, we formalize the cross-domain recommendation problem, unify the perspectives from which it has been addressed, analytically categorize, describe and compare prior work, and identify open issues for future research.
Measuring the concentration profiles induced by gravity settling is known to be an efficient route to obtain the equation of state of a colloidal suspension, to inspect the fine details of the phase diagram and to provide clues on the nature of metastable phases. Here we show that a careful analysis of the transient settling profiles may add valuable information for what concerns colloidal hydrodynamics. In particular, we show that a numerical inversion of a kinetic profile yields the full hydrodynamic factor K () up to the concentration of the original unsettled suspension, and that the dilute part of the profile yields a 'dynamic' gravitation length also related to K (). These predictions are tested on a suspension of monodisperse hard and sticky spheres. Finally we describe and test a novel optical method, allowing us to measure sedimentation profiles on a wide class of colloidal systems, even in the presence of a noticeable turbidity.
The photoreduction of CO2 is an intriguing process which allows the synthesis of fuels and chemicals. One of the limitations for CO2 photoreduction in the liquid phase is its low solubility in water. This point has been here addressed by designing a fully innovative pressurized photoreactor, allowing operation up to 20 bar and applied to improve the productivity of this very challenging process. The photoreduction of CO2 in the liquid phase was performed using commercial TiO2 (Evonink P25), TiO2 obtained by flame spray pyrolysis (FSP) and gold doped P25 (0.2 wt% Au-P25) in the presence of Na2SO3 as hole scavenger (HS). The different reaction parameters (catalyst concentration, pH and amount of HS) have been addressed. The products in liquid phase were mainly formic acid and formaldehyde. Moreover, for longer reaction time and with total consumption of HS, gas phase products formed (H2 and CO) after accumulation of significant number of organic compounds in the liquid phase, due to their consecutive photoreforming. Enhanced CO2 solubility in water was achieved by adding a base (pH = 12–14). In basic environment, CO2 formed carbonates which further reduced to formaldehyde and formic acid and consequently formed CO/CO2 + H2 in the gas phase through photoreforming. The deposition of small Au nanoparticles (3–5 nm) (NPs) onto TiO2 was found to quantitatively influence the products distribution and increase the selectivity towards gas phase products. Significant energy storage in form of different products has been achieved with respect to literature results.
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