Pt-supported La1–x Sr x CoO3 and Pt-doped La1–x Sr x CoO3 are synthesized using chemical reduction and solution combustion method, respectively. Chemical reduction is carried out using formaldehyde as a reducing agent giving Pt-supported La1–x Sr x CoO3. Solution combustion method is used to prepare Pt-doped La1–x Sr x CoO3. Detailed characterization using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Brunauer–Emmett–Teller (BET) surface area measurement, and transmission electron microscopy (TEM) is carried out to distinguish the Pt-supported and Pt-doped compounds in terms of their morphology and Pt oxidations states. TEM results indeed show the differences in their morphology. Further, electrochemical measurements are performed in neutral medium to differentiate their electrochemical activity. Cyclic voltammetry (CV) shows noticeable differences between Pt-supported La1–x Sr x CoO3 and Pt-doped La1–x Sr x CoO3. Importantly, our results show that Pt4+ in doped compound has poor to zero electrocatalytic activity toward formic acid and methanol electro-oxidation in comparison to Pt0 in supported compound. This study shows that metallic Pt in zero oxidation state is a superior catalyst to Pt in +4 oxidation state.

The figure of merit (zT) of a thermoelectric material can be enhanced by incorporation of nanoinclusions into bulk material. The presence of bismuth telluride (Bi2Te3) nanoinclusions in Co4Sb12 leads to lower phonon thermal conductivity by introducing interfaces and defects; it enhances the average zT between 300-700 K. In the current study, Bi2Te3 nanoparticles were dispersed into bulk Co4Sb12 by ball-milling. The bulk was fabricated by spark plasma sintering (SPS). The presence of Bi2Te3 dispersion in Co4Sb12 was confirmed by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and electron back scattered diffraction (EBSD) technique. Energy dispersive spectroscopy (EDS) showed antimony (Sb) as an impurity phase for higher contents of Bi2Te3 in the sample. The Seebeck coefficient (S) and electrical conductivity () were measured in the temperature range of 350 - 673 K. The negative value of S indicates that most of the charge carriers were electrons. A decrease in S and increase in with Bi2Te3 content are due to the increased carrier concentration, as confirmed by Hall measurement. The thermal conductivity, measured between 423 - 673 K, decreased due to the increased phonon scattering at interfaces. A maximum zT of 0.17 was achieved at 523 K and it did not vary much throughout the temperature range. The experimental results of composites were compared by using effective medium theories.

Aerospace-grade Ni-based alloys such as Inconel 718 and 625 are widely used in the airspace industry thanks to their excellent mechanical properties at high temperatures. However, these materials are classified as 'difficult-to-machine' because of their high shear strength, low thermal conductivity, tendency to work-harden and presence of carbide particles in their microstructure, which lead to rapid tool wear. Machining-induced residual stresses in a machined part is an important parameter which is assessed since it can be used to evaluate overall structural resilience of the component and its propensity to fatigue failure in-service. Ultrasonically assisted turning (UAT) is a hybrid machining technique, in which tool-workpiece contact conditions are altered by imposing ultrasonic vibration (typical frequency~20 kHz) on a tool's movement in a cutting process. Several studies demonstrated successfully the resulting improvements in cutting forces and surface topography. However, a thorough study of UATinduced residual stresses is missing. In this study, experimental results are presented for machining Inconel 718 and 625 using both conventional turning (CT) and UAT with different machining parameters to investigate the effect on cutting forces, surface roughness and residual stresses in the machined parts. The study indicates that UAT leads to significant cutting force reductions and improved surface roughness in comparison to CT for cutting speeds below a critical level. The residual stresses in machined workpiece show that UAT generates more compressive stresses when compared to those in CT. Thus, UAT demonstrates an overall improvement in machinability of Inconel alloys.

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