No abstract

Forward osmosis (FO) technology for desalination has been extensively studied due to its immense benefits over conventionally used reverse osmosis. However, there are some challenges in this process such as a high reverse solute flux (RSF), low water flux, and poor chlorine resistance that must be properly addressed. These challenges in the FO process can be resolved through proper membrane design. This study describes the fabrication of thin-film composite (TFC) membranes with polyethersulfone solution blown-spun (SBS) nanofiber support and an incorporated selective layer of graphene quantum dots (GQDs). This is the first study to sustainably develop GQDs from banyan tree leaves for water treatment and to examine the chlorine resistance of a TFC FO membrane with SBS nanofiber support. Successful GQD formation was confirmed with different characterizations. The performance of the GQD-TFC-FO membrane was studied in terms of flux, long-term stability, and chlorine resistance. It was observed that the membrane with 0.05 wt.% of B-GQDs exhibited increased surface smoothness, hydrophilicity, water flux, salt rejection, and chlorine resistance, along with a low RSF and reduced solute flux compared with that of neat TFC membranes. The improvement can be attributed to the presence of GQDs in the polyamide layer and the utilization of SBS nanofibrous support in the TFC membrane. A simulation study was also carried out to validate the experimental data. The developed membrane has great potential in desalination and water treatment applications.

Worldwide water shortage and significant issues related to treatment of wastewater streams, mainly the water obtained during the recovery of oil and gas operations called produced water (PW), has enabled forward osmosis (FO) to progress and become advanced enough to effectively treat as well as retrieve water in order to be productively reused. Because of their exceptional permeability qualities, thin-film composite (TFC) membranes have gained increasing interest for use in FO separation processes. This research focused on developing a high water flux and less oil flux TFC membrane by incorporating sustainably developed cellulose nanocrystal (CNC) onto the polyamide (PA) layer of the TFC membrane. CNCs are prepared from date palm leaves and different characterization studies verified the definite formations of CNCs and the effective integration of CNCs in the PA layer. From the FO experiments, it was confirmed that that the membrane with 0.05 wt% of CNCs in the TFC membrane (TFN-5) showed better FO performance in PW treatment. Pristine TFC and TFN-5 membrane exhibited 96.2% and 99.0% of salt rejection and 90.5% and 97.45% of oil rejection. Further, TFC and TFN-5 demonstrated 0.46 and 1.61 LMHB pure water permeability and 0.41 and 1.42 LHM salt permeability, respectively. Thus, the developed membrane can help in overcoming the current challenges associated with TFC FO membranes for PW treatment processes.