A new diluted magnetic III-V semiconductor of In& -Mn"As (x~0.18) bas been produced by molecular-beam epitaxy. Films grown at 300 C are predominantly ferromagnetic and their properties suggest the presence of MnAs clusters. Films grown at 200 C, however, are predominantly paramagnetic, and the lattice constant decreases with increasing Mn composition; both are indicative of the formation of a homogeneous alloy. These films have n-type conductivity and reduced band gaps.PACS numbers: 75.50.Pp, 68.55.Bd, 73.60.Br Diluted magnetic semiconductors are semiconductors in which a sizable fraction of the component ions are replaced by those of transition metals or rare earths, leading to a variety of cooperative effects. Most importantly, the state of magnetization changes the electronic properties (and vice versa) through the spin-exchange interaction between local magnetic moments and carriers. ' Rare-earth and transition-metal chalcogenides have been the most widely studied magnetic semiconductors.For example, mixed crystals (alloys) can be formed over a wide range of compositions even if the crystal structures of the two component materials are different from each other, as exemplified by the ternary alloy Cd& "Mn"Te. Among magnetic ions, many of the transition elements, particularly Mn + which tends to assume a spherically symmetric magnetic ground state, can be accommodated in the zinc-blende structure by substituting group-II cations in the II-VI compounds. In this paper, in contrast, we are concerned with the incorporation of high concentrations of tnagnetic ions in III-V compound semiconductors. Up to now, the number of magnetic ions incorporated in III-V semiconductors has been limited to doping levels 10' -10' cm, beyond which surface segregation and, in extreme cases, phase separation occur and impede further incorporation of the magnetic ions into the crystals. These experiments imply that the preparation of ternary alloys to form diluted magnetic III-V semiconductors is an extremely difficult task. We consequently sought to study metastable solid phases using the diverse growth-parameter space provided by the molecular-beam-epitaxy technique. In this situation, the preparation of the material itself includes such fundamental subjects as solubility, stability of the resulting crystal structures, the valence state of the magnetic ions, and the associated magnetism, all of which are not usua11y encountered in isovalent semiconductor alloy systems.Through the preparation and characterization of epitaxial 61ms of InMnAs, we obtained experimental evidence for the formation of a III-V-based diluted magnetic semiconductor in which a large amount of Mn is incorporated at least up to an average composition of In/Mn/As 0.82/0. 18/1.0. Studying magnetic, metallurgical, and semiconducting properties, we 6nd that the 61ms may be classi6ed into two different groups depending on the growth temperature. Films grown at relatively high temperatures (-300'C) exhibit ferromagnetic behavior similar to that of MnAs which may ex...
Waveguide structures and couplers for x rays are analyzed. Experimental results are given for the propagation of Cu Ka radiation in guides made of BN.
We demonstrate that lanthanum gallate (LaGaO3) has considerable potential as an electronic substrate material for high-temperature superconducting films. It provides a good lattice and thermal expansion match to YBa2Cu3O7−x, can be grown in large crystal sizes, is compatible with high-temperature film processing, and has a reasonably low dielectric constant (ε≂25) and low dielectric losses. Epitaxial YBa2Cu3O7−x films grown on LaGaO3 single-crystal substrates by three techniques have zero resistance between 87 and 91 K.
Crystallographic parameters, Curie points, and freezing temperatures are presented for a series of A'A,"+Nb50i5 compositions with tungsten bronze-related structures, where A'=Na, K, or Rb, and A2+=Sr or Ba. Results are also reported for bronze solid solutions in the systems KNb0,-PbNb,O,, K (Sr-Ba) zNb60i5, K( Ba-Pb) zNb50i6, K(Sr-Pb)zNb6015, and (KSrz-KzLa)Nb5O15. On the basis of these data, an empirical relation is shown between the ferroelectric transition temperature, Tc, and axial ratio V-13 co/ao. The T o vs V% c 0 / a curve for compositions with polar axes perpendicular to [OOll has a negative slope, whereas that for compositions with polar axes parallel to 100lj has a positive slope of about the same magnitude. These results are compared with measurements of the temperature dependence of co/uo for KSrPbNbsOi, and KBa,Nb,O,,; the latter is discussed in terms of the Devonshire free energy theory.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.