Liquid water is one of the most studied but still one of the least understood substances. The absorption spectra of water in the mid-IR were measured from -10 and up to 90 degrees C using fiberoptic evanescent wave spectroscopy. The changes in the spectrum and the existence of an isosbestic point during the ice-liquid phase transition were studied. Based on the spectroscopic data we propose a multispecies model for the structure of liquid water. The new model provides an explanation for the results of the measurements reported in this work. It also provides an explanation for some of the unique thermodynamic and kinetic properties of liquid water and for many of the anomalies of water.

Measurements of mid-infrared (MIR) absorption spectra of water and heavy water were carried out by fiber-optic evanescent wave spectroscopy, using silver halide (AgClBr) infrared fibers. Such measurements were performed for the first time on one sample, during the solid-liquid phase transition. From the variation of the spectra with temperature we found a new isosbestic point (at 3280 cm(-1) for H(2)O or at 2475 cm(-1) for D(2)O) and we identified five components of the O-H (O-D) stretch band. These phenomena have provided new information about the molecular structure of water.

There is an interest in single-mode fibers that are highly transparent in the middle infrared. Such fibers would be valuable for spectroscopy, interferometry, fiber lasers, and heterodyne detection. We developed core-clad fibers made of crystalline silver halides, with external diameter 900 μm, small core diameters (50–60 μm) and an extremely small difference (∼0.004) between the indices of refraction of the core and the clad. These fibers behaved as single-mode fibers at the wavelength 10.6 μm.