Two-dimensional
transition metal dichalcogenide semiconductors are intriguing hosts
for quantum light sources due to their unique optoelectronic properties.
Here, we report that strain gradients, either unintentionally induced
or generated by substrate patterning, result in spatially and spectrally
isolated quantum emitters in mono- and bilayer WSe2. By
correlating localized excitons with localized strain variations, we
show that the quantum emitter emission energy can be red-tuned up
to a remarkable ∼170 meV. We probe the fine-structure, magneto-optics,
and second-order coherence of a strained emitter. These results raise
the prospect of strain-engineering quantum emitter properties and
deterministically creating arrays of quantum emitters in two-dimensional
semiconductors.
Torsional stress generated during DNA replication and transcription has been suggested to facilitate nucleosome unwrapping and thereby the progression of polymerases. However, the propagation of twist in condensed chromatin remains yet unresolved. Here, we measure how force and torque impact chromatin fibers with a nucleosome repeat length of 167 and 197. We find that both types of fibers fold into a left-handed superhelix that can be stabilized by positive torsion. We observe that the structural changes induced by twist were reversible, indicating that chromatin has a large degree of elasticity. Our direct measurements of torque confirmed the hypothesis of chromatin fibers as a twist buffer. Using a statistical mechanicsbased torsional spring model, we extracted values of the chromatin twist modulus and the linking number per stacked nucleosome that were in good agreement with values measured here experimentally. Overall, our findings indicate that the supercoiling generated by DNAprocessing enzymes, predicted by the twin-supercoiled domain model, can be largely accommodated by the higher-order structure of chromatin.
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