We have measured microrheological and microstructural properties of a superparamagnetic ferrofluid made of Mn0.75Zn0.25Fe2O4 (MZF) nanoparticles, using passive microrheology in a home-built inverted microscope. Thermal motion of a probe microsphere was measured for different values of an applied external magnetic field and analysed. The analysis shows anisotropy in magneto-viscous effect. Additional microrheological properties, such as storage modulus and loss modulus and their transition are also seen. We have also obtained microstructural properties such as elongational flow coefficient [Formula: see text] , relaxation time constant [Formula: see text] , coefficient of dissipative magnetization [Formula: see text] , etc., using the analysis given in Oliver Muller et al., J. Phys.: Condens. Matter 18, S2623, (2006) and Stefan Mahle et al., Phys. Rev. E 77, 016305 (2008) over our measured viscosity data. Our values for the above parameters are in agreement with earlier theoretical calculations and macro-rheological experimental measurements. These theoretical calculations consider an ideal situation of zero-shear limit, which is best approximated only in the passive microrheology technique described here and a first time measurement of all these parameters with passive microrheology.

Particle tracking with a 0.98µm silica sphere is used in determining precessional motion of nematic director in nematic phase of 8CB liquid crystals, as it probes those oriented structures which are of the same wavelength as of the sphere size. Velocity auto correlation(VACF) is used in determining those structures in both parallel and perpendicular orientations to the neamatic director. Further, a generic approach by considering the time dependent harmonic oscillator motions is used to analyze the VACF distribution function. This approach leads to observe a transition in the structures of nematic phase that are comparable to transformations from underdamped harmonic oscillator motion to critically damped motion. Also, we measured the microstructural properties and calculated micromechanical properties. The experimental analysis approach used here for 8CB liquid crystals helps to understand and characterize the general dynamic behavior of complex fluids. With this analysis, 'dynamics of complex fluids' becomes no more 'complex'.