In the present work, the contemporary exhaust gas treatment systems (EGTS) used for SOx, PM, and NOx emission mitigation from shipping are reviewed. Specifically, after-treatment technologies such as wet scrubbers with seawater and freshwater solution with NaOH, hybrid wet scrubbers, wet scrubbers integrated in exhaust gas recirculation (EGR) installations, dry scrubbers, inert gas wet scrubbers and selective catalytic reduction (SCR) systems are analyzed. The operational principles and the construction specifications, the performance characteristics and the investment and operation of the reviewed shipping EGTS are thoroughly elaborated. The SCR technology is comparatively evaluated with alternative techniques such as LNG, internal engine modifications (IEM), direct water injection (DWI) and humid air motor (HAM) to assess the individual NOx emission reduction potential of each technology. Detailed real data for the time several cargo vessels spent in shipyards for seawater scrubber installation, and actual data for the purchase cost and the installation cost of seawater scrubbers in shipyards are demonstrated. From the examination of the constructional, operational, environmental and economic parameters of the examined EGTS, it can be concluded that the most effective SOx emission abatement system is the closed-loop wet scrubbers with NaOH solution which can practically eliminate ship SOx emissions, whereas the most effective NOx emission mitigation system is the SCR which cannot only offer compliance of a vessel with the IMO Tier III limits but can also practically eliminate ship NOx emissions.

In the present study, energy and exergy analyses of a simple supercritical, a split supercritical and a cascade supercritical CO2 cycle are conducted. The bottoming cycles are coupled with the main two-stroke diesel engine of a 6800 TEU container ship. An economic analysis is carried out to calculate the total capital cost of these installations. The functional parameters of these cycles are optimized to minimize the electricity production cost (EPC) using a genetic algorithm. Exergo-economic and exergo-environmental analyses are conducted to calculate the cost of the exergetic streams and various exergo-environmental parameters. A parametric analysis is performed for the optimum bottoming cycle to investigate the impact of ambient conditions on the energetic, exergetic, exergo-economic and exergo-environmental key performance indicators. The theoretical results of the integrated analysis showed that the installation and operation of a waste heat recovery optimized split supercritical CO2 cycle in a 6800 TEU container ship can generate almost 2 MW of additional electric power with a thermal efficiency of 14%, leading to high fuel and CO2 emission savings from auxiliary diesel generators and contributing to economically viable shipping decarbonization.

A thermo-economic analysis of a regenerative dual-loop organic Rankine cycle (ORC) is conducted, which will be coupled with the main diesel engines of a general support vessel. An energy and exergy analysis of the regenerative dual-loop ORC is conducted. The energy and exergy analysis results of the regenerative dual-loop ORC are compared with pertinent results for a simple dual-loop ORC without regeneration. A mission analysis that was based on a vessel speed profile with the proposed ORC was conducted. A heat transfer analysis was performed for dimensioning the heat exchangers of both ORC loops. Finally, an economic analysis is conducted to calculate the total capital cost and the payback period of the proposed ORC. The results showed that the proposed ORC is thermodynamically superior in both energetic and exergetic terms compared to the simple dual-loop ORC. The total fuel cost saving is 337,493 Euros, the total CO2 emission saving is 1,153,416.4 kg, and the SO2 emission saving is 36,044.3 kg. The total capital cost of the proposed ORC is 2,546,000 Euros. Finally, the installation of the proposed ORC in the examined vessel is economically feasible because it results in a reasonable payback period, which is less than nine years.

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