Despite the enormous interest in superhydrophobicity for self-cleaning, a clear picture of contaminant removal is missing, in particular, on a single-particle level. Here, we monitor the removal of individual contaminant particles on the micrometer scale by confocal microscopy. We correlate this space-and time-resolved information with measurements of the friction force. The balance of capillary and adhesion force between the drop and the contamination on the substrate determines the friction force of drops during self-cleaning. These friction forces are in the range of micro-Newtons. We show that hydrophilic and hydrophobic particles hardly influence superhydrophobicity provided that the particle size exceeds the pore size or the thickness of the contamination falls below the height of the protrusions. These detailed insights into self-cleaning allow the rational design of superhydrophobic surfaces that resist contamination as demonstrated by outdoor environmental (>200 days) and industrial standardized contamination experiments.

When a water drop slides over a hydrophobic surface, it usually acquires a positive charge and deposits the negative countercharge on the surface. Although the electrification of solid surfaces induced after contact with a liquid is intensively studied, the actual mechanisms of charge separation, so-termed slide electrification, are still unclear. Here, slide electrification is studied by measuring the charge of a series of water drops sliding down inclined glass plates. The glass was coated with hydrophobic (hydrocarbon/fluorocarbon) and amine-terminated silanes. On hydrophobic surfaces, drops charge positively while the surfaces charge negatively. Hydrophobic surfaces coated with a mono-amine (3-aminopropyltriethyoxysilane) lead to negatively charged drops and positively charged surfaces. When coated with a multiamine ( N -(3-trimethoxysilylpropyl)diethylenetriamine), a gradual transition from positively to negatively charged drops is observed. We attribute this tunable drop charging to surface-directed ion transfer. Some of the protons accepted by the amine-functionalized surfaces (−NH 2 with H + acceptor) remain on the surface even after drop departure. These findings demonstrate the facile tunability of surface-controlled slide electrification.

Super liquid repellent coatings are among the most promising candidates for selfcleaning surfaces for indoor and outdoor applications. However, the characteristic nano-and micro-scale protrusions can easily be damaged. Improving the durability of these coatings belongs to the most important challenges to increase the coating's application potential. Here, we show that commercial polyester fabrics coated with silicone nanofilaments maintain their self-cleaning properties throughout repeated freezing-unfreezing cycles, ironing, and mechanical stress. The coating improves the heat resistance of the fabric. The surface keeps its water repellency until the fabric is almost destroyed by scratching with sandpaper or a metal sponge. The excellent performance results from the synergetic effects of i) the interwoven structure of the fabric and ii) the intrinsic hydrophobic and flexible nature of the fabric and of the nanofilaments coating. The combination of these factors generates a product which overcomes the most claimed drawbacks of super liquid repellent coatings.

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