The zirconium alloys ZrNbMoGe have been developed with the aim to improve its high temperature oxidation for employment as a cladding material in Pressurized Water Reactor (PWR) and to extend the over all fuel burn-up. In this paper the effect of Cu addition on the high temperature oxidation behavior of ZrNbMoGe alloy was investigated. The zirconium alloy was produced by melting the zirconium-niobium-molybdenum-germanium and copper-sponge in an arc furnace in an argon environment by the temperature higher than 1850C. The weight percentages of the elements were 2.50 wt.% Nb, 0.5 wt.% Mo, 0.1 wt.% Ge, 0.5 wt.% Cu and Zr in balanced. The oxidation test was carried out in the Magnetic Suspension Balance (MSB) workstation. Two specimens of ZrNbMoGe alloys without and with Cu addition were oxidized in atmosphere at temperature of 500 °C and 700 °C for 8 hours. The results show the oxidation kinetics followed the parabolic rate law. The difference of oxidation behaviors of the two specimens were considered to be caused by the formation of different kind of oxide layers due to the Cu addition.
Austenitic ODS (Oxide Dispersion Strengthened) 316L steel was fabricated using 316L SS (Stainless Steel) pre-alloyed powder and yttria powders by mechanical milling with APS (Arc Plasma Sintering) method. The powders were milled in High Milling Shaker at 1000 rpm in rotational speed for 10 hours at 10 BPR (Ball Powder Ratio). As milled powders were pressed at 20 Ton and sintered with APS for 0 to 12 minutes at 70 A. The samples were analysed using X-Ray Diffraction (XRD), Microscope Optic (MO) with micro-hardness tester and Scanning Electron Microscope – Energy Dispersive X-Ray Spectroscope (SEM-EDS). The results of phase and microstructure showed the austenitic grade of the samples. The sintering time contributed to the microstructure of the samples. At room temperature, the mechanical properties of ODS 316L SS was higher than conventional 316L SS.
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