Nickel hydrazine nitrate is an energetic coordination compound having explosive properties in between that of primary and secondary. This compound was used to develop a new type of detonator by replacing the sensitive primary explosive, lead azide in conventional detonators and keeping RDX (cyclotrimethylenetrinitramine) as the output secondary explosive. The detonator consists of three regions, viz., initiation, deflagration-to-detonation transition (DDT), and output. The initiation and the electrical rating of 1A/1W no-fire were achieved using a suitable squib. The DDT and the output were taken care of, by pressing requisite quantities of Nickel hydrazine nitrate and RDX, respectively at required densities in a stainless steel stem channel. The detonator assembly involves crimping the squib and the stem channel in a stainless steel housing and applying a suitable resin at the crimped-end for leak tightness. The output was assessed from the dent depth on aluminium plate, volume expansion on lead block, and by achieving veloctiy of detonation of 8200 m/s in mild detonating cords, containing 0.95 g/m of RDX, which indicates full-order detonation. The detonators were tested at system level and found to perform satisfactorily.
Boron-potassium nitrate (B-KNO 3 ) (25/75) is a well-known pyrotechnic composition which finds application as energy-release system for small-calibre rockets and pyrogen igniters for larger motors. The decomposition of the oxidiser in this composition is endothermic which can be activated by the addition of high explosives, which decompose exothermically. This paper describes the influence of two nitramine explosives, RDX and HMX, on the ignition characteristics of B-KNO 3 composition using thermogravimetry, differential scanning calorimetry, heat and pressure output measurements. Different compositions were prepared by varying the amount of RDX/HMX from 10 per cent to 50 per cent. Thermal studies on the B-KNO 3 /high explosive mixtures reveal that these undergo two-stage decomposition. The first stage corresponds to the decomposition of high explosive and the second stage corresponds to that of the reaction between B and KNO 3 . Kinetic parameters were calculated for both the stages of TG curves using CoatsRedfern and Mac Callum-Tanner methods. Ignition temperature of B-KNO 3 decreases on the addition of RDX/HMX while the onset of RDX or HMX decomposition is not significantly affected by B-KNO 3 . The pressure output of B-KNO 3 increases on adding RDX/HMX. The heat output of B-KNO 3 is not much affected by the addition of RDX or HMX, even though the heat of explosion of RDX and HMX are low. This is due to the reaction between the combustion products of RDX/HMX and reaction products of B-KNO 3 to form more exothermic products like B 2 O 3 , releasing extra heat. The flame temperature of the charge increases while the average molecular weight of the products of combustion decreases as the RDX/HMX content increases. Thus, the charge, on addition of RDX or HMX, produces higher pressure output, maintaining the heat output at comparable levels.
A gas generating composition (GGC) was designed with Guanidinium azotetrazolate (GZT) as fuel and Ammonium perchlorate (AP) as an oxidizer for burst testing of nozzle closure at rig level, simulating solid rocket motor ignition transient and propellant flame temperature. EXPLO5 software code was used for formulation studies. The selected GGC formulation was subjected to thermokinetic analysis for understanding the thermal decomposition behaviour as well as evaluating kinetic and thermodynamic parameters of decomposition.The non‐isothermal kinetic parameters of the composition over the extent of conversion were determined using two isocoversional methods viz; Flynn‐Wall‐Ozawa (FWO) and Kissinger–Akahira–Sunose (KAS). GGC in pellet form was fired using a pyrotechnic pressure generating device (PPG) in test rig level with nozzle closure. The nozzle closure was burst opened at a pressure of 0.985 MPa with a pressurization rate of 10.3 MPa s−1.
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