The paper is devoted to the study of waste processing of shungite rocks, which are formed in the process of mining and technological operations. However, the market of national modifying additives based on local raw materials is not developed at the appropriate level in the presence of a rich resource base of the mining industry. In this regard, it is of great interest to obtain additives based on shungite rock processing waste, which allow expanding the range of mineral additives and providing qualitatively new properties for concrete and reinforced concrete products and structures. Such technologies for the production of additives are isolated and not developed at the proper level due to insufficient knowledge of shungite rocks. Analysis of the state of research on concrete and the market for modifying materials showed that the development of production of energy-efficient and environmentally friendly materials due to increasing regulatory requirements for them, as well as to environmental ecology and the obvious need to recycle industrial waste initiated the progressive development of concrete science. One of its latest achievements is modified concrete with special properties, which marked a new stage in the development of concrete. In its production technology, significant progress has been made in improving its chemical additives, special modifiers, as well as active and inactive fillers. In Kazakhstan, the main volume of modifying additives is imported from abroad, which significantly increases their cost, so their choice is limited. This paper is devoted to the research of waste processing of shungite rocks as a modifying mineral additive of concrete. Its influence on the main indicators of concrete is investigated and the features of the processes that occur in the hardening silicate system “cement - dispersed shungite particles” and contribute to increasing the strength of concrete, as well as reducing the duration of its heat-and-water treatment are studied.
A method of producing portland cement using the wastes of enrichment of polymetallic ores of "Achpolymetal" (Kentau, Kazakhstan) in the amount of 0.5 to 2.5% as a mineralizing additive in the raw mixture is proposed. This allows the clinker to be produced at a lower temperature (1300–1350 °C), resulting in lower fuel consumption and higher furnace productivity. The experimental clinker is better subjected to grinding, the electric power consumption for grinding cement decreases, the grinding bodies of cement mills decrease. In the waste, there are catalytic and modifying elements. Studies have shown that in the no-added raw mix the clinker formation processes are completed at 1450 °C. When 0.5 to 2.0% of the tailings are introduced, the complete binding of CaO is completed at 1400 °C, with the addition of 2.5% of tailings, lime binding is completed at 1300 or 150 °C lower than in the control non-additive raw mixture. In clinkers, only 1.09–1.32 % of free lime remains. The strength of cement when introduced into the raw mix from 0.5 to 2.0% of barite waste is increased. The compressive strength at 28 days of age for cement with an optimum dosage of 1‒2% of the tail increases from 414 kg/cm2 to 430‒432 kg/cm2 or by 3.9‒4.3%. Similarly, the strength of steamed samples increases by 4.7‒5.7%.
The article presents the obtaining results of clinkers of sulfate resistant and road cement during the production tests process. The usage of man-made wastes such as lead slag, coal mining waste as well as clay component and additives. X-ray, chemical analyzes of starting materials, clinkers and obtained cements were carried out. The regularities of charge compositions, saturation coefficient, modules, burning regimes on chemical and mineralogical composition and quality of clinkers and cements, improvement of rotary kiln operation, reduction of greenhouse gas emissions and fuel consumption are established. Various methods of analysis were used, calculations of raw mixtures composition were carried out according to the program "Shikhta" (designed to calculate the raw mix and the mineralogical composition of the clinker for the production of Portland cement. The program was developed in the V.G. Shukhov Belgorod State Technical University, Russia) and "Calculation of raw mixtures or CRM" (designed to calculate the raw mix of clinker. The program was developed in the M. Auezov South-Kazakhstan State University, Kazakhstan). The strength of factory and experimental cements was tested after 3, 7 and 28 days and after steaming.
The article analyzes the use of polymetallic ores' tailings as a basis for production of composite cements and concrete, having protective properties against gamma and X-rays radiation, as well as high strength and lifetime. The main practically significant result is: the development of scientific and technological production bases of new high-tech type of multicomponent hydraulic binders for concretes -composite cements; the identification of new hydration products in composite cements with addition of polymetallic ores' tailings; the development of optimal compositions of composite cements for concretes. It is established that the composite cements, that developed by us on the basis of polymetallic ores' tailings, meet modern requirements i.e. its improve the construction-technical properties of material, have positive effect to the environment situation and allow to reduce the production cost of the final product. Their technology is low metal-intensive and power-consuming. Studies of physical-chemical processes of composite cements structure formation with addition of polymetallic ores' tailings have been conducted using methods such as chemical, X-ray phase, differential-thermal and electronmicroscopic analysis methods.
<p>We have carried out studies on the production of low-clinkered floured cements (LCFC) on the basis of natural and technogenic waste. The research on optimizing the compositions, strength, durability and performance properties of low-clinkered floured cements (LCFC) was carried out. Therefore, we studied the new products in the process of hydration of mechanically activated multi-component cements in the presence of technogenic wastes of the industry (waste of limestone crushing at opencast mines, metallurgical and phosphoric slag) and surface-active reagents (SAR) (superplasticizer S-3); as well as the development of compositions of high-strength and technological sorts of cement concretes. Thus, the low-clinkered floured cements developed by us based on industrial technogenic waste that meet the modern requirements, i.e. they improve physical-mechanical characteristics of the material and positively influence the ecological situation and allow decreasing the cost of final product. The physico-chemical research of the processes of hydration of low-clinkered floured cements with additive of superplasticizer S-3 were carried out by modern methods using X-ray diffract-meter D8ADVANCE (Bruker company) with Cu-radiation and synchronous thermo-analyzer STA 409 PC Luxx (Netzsch, Germany) at exposure mode of 10 º/min in the platinum crucibles in the air conditions.</p>
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