(1) Hydroxyapatite (Hap), which can be obtained by several methods, is known to be a good adsorbent. Coal fly ash (CFA) is a commonly reused byproduct also used in environmental applications as an adsorbent. We sought to answer the following question: Can CFA be included in the method of Hap wet synthesis to produce a composite capable of adsorbing both heavy metals and dyes? (2) High calcium lignite CFA from the thermal power plant in Bełchatów (Poland) was used as the base to prepare CFA–Hap composites. Four types designated CFA–Hap1–4 were synthesized via the wet method of in situ precipitation. The synthesis conditions differed in terms of the calcium reactants used, pH, and temperature. We also investigated the equilibrium adsorption of Cu(II) and rhodamine B (RB) on CFA–Hap1–4. The data were fitted using the Langmuir, Freundlich, and Redlich–Peterson models and validated using R2 and χ2/DoF. Surface changes in CFA–Hap2 following Cu(II) and RB adsorption were assessed using SEM, SE, and FT-IR analysis. (3) The obtained composites contained hydroxyapatite (Ca/P 1.67) and aluminosilicates. The mode of Cu(II) and RB adsorption could be explained by the Redlich–Peterson model. The CFA–Hap2 obtained using CFA, Ca(NO3)2, and (NH4)2HPO4 at RT and pH 11 exhibited the highest maximal adsorption capacity: 73.6 mg Cu/g and 87.0 mg RB/g. (4) The clear advantage of chemisorption over physisorption was indicated by the Cu(II)–CFA–Hap system. The RB molecules present in the form of uncharged lactone were favorably adsorbed even on strongly deprotonated CFA–Hap surfaces.
This paper presents the results of a study on the development of a Metal active gas (MAG) welding technology for an industrial furnace component made of steel S235JRC+N with respect to the minimizationof welding deformation. A numerical simulation of the welding process was performed in the first phase of the research. The numerical simulation was carried out with the SYSWELD software. For the numerical simulation of the welding process, the FEM method was used. In the simulation, four variants of restraint of the industrial furnace wall panel elements during the execution of the welding process were investigated. They differed in the number of restraints (model 1–4). It was found that the difference between the maximum mean strain in model 1 and the lowest mean strain in model 4 was only 11%. A physical simulation of the welding process was then performed with a restraint variant according to model 1. The displacement results obtained from the physical simulation of the welding process were compared with the displacement results from the numerical simulation. Discrepancies between numerical and physical simulation displacement values were found. The quality of selected welded joints was also evaluated. Visual testing (VT) and measurements of weld geometries were performed for this purpose. Metallographic tests and hardness measurements were performed to determine of influence of the welding process on the microstructure of the welded joint area, especially the heat affected zone (HAZ). The results obtained confirm the correctness of the assumptions made regarding the technology of manufacturing the furnace wall panels.
NC11 steel, in view of the specificity of its manufacturing process, is characterised with band-like orientation of carbides. Depending on the direction of cutting the material for the inserts out of commercially available steel products, carbide bands can be oriented in parallel or perpendicularly to the direction in which aggregate grains move in the process of pressing stampings. It has been found that in case of scratches made in direction perpendicular to carbide bands, depth of the scratches is less than this observed when scratches are made in direction coinciding with prevailing orientation of carbide precipitates.
This paper presents the results of tests on the fabrication of welded joints in S1300QL steel according to the requirements of ISO 15614-14 and ISO 12932. The butt-welded joint without bevel was made from 350 × 150 × 8 mm sheets. The welding process was carried out at the hybrid welding (laser–MAG) station. MAG means metal active gas. The test welded joints were subjected to non-destructive and destructive testing. Visual and radiographic examinations were carried out. The distribution of HV10 hardness was determined in the weld, the heat-affected zone, and the base material. The microstructure of these areas was also analysed for the presence of hard and brittle hardening products and non-metallic inclusions. Tensile strength and yield strength, as well as bending strength, were assessed in the mechanical property tests. The impact test was performed in accordance with ISO 9016.
The paper presents results of assessment of the unit pressure force within the refractory material volume in the course press-moulding of stampings for refractory precast shapes. The force was evaluated with the use of physical simulation of deformation undergone by lead balls placed in the raw refractory mass subjected to pressing in a metal die. To determine the value of unit pressure force applied to the aggregate grains in the course of stamping press-moulding, physical model of deformation of a sphere induced by the uniaxial stress state was used.
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