This paper presents the results of research on obtaining biochar from agricultural plant waste such as rice husk and straw. The selection of the optimal conditions for thermolysis, such as the duration and temperature of the process, has been conducted. The thermolysis products are characterized for iodine adsorption activity, cumulative water pore volume, and for bulk density. The porous structure of the obtained products has been studied by scanning electron microscopy. Based on the results of the research conducted, it has been found that biochars obtained from husk and straw with a thermolysis duration of 30 minutes have low iodine sorption characteristics and water pore volumes. With an increase in the duration of thermolysis, the sorption characteristics improve, the optimal for the husk is the thermolysis duration of 60 minutes at a temperature of 500°C, and for straw, the optimal thermolysis duration is 60 minutes at a temperature of 300°C. The best option is biochar obtained from rice straw at a duration of 60 minutes and a thermolysis temperature of 300°C, having an iodine adsorption activity of 54.61%, a cumulative water pore volume of 0.941 cm3/g and a bulk density of 169.29 g/dm3. The obtained biochars from rice husk and straw have been studied by scanning electron microscopy at 4300 and 5000 times magnification, and they have a developed porous structure. According to the literature, it is known that biochar can also be used as a renewable energy source. Research has been carried out to determine the calorific value of the obtained biochars. To compare the calorific value of rice husk, straw and the obtained biochars, their heating values have been determined on a calorimeter. The highest heating value has a biochar obtained from husk at a duration of 60 minutes and at a thermolysis temperature of 400°C with a value of 17.520 kJ/g, the optimal for biochar obtained from straw is a duration of 60 minutes and a thermolysis temperature of 400°C with a value of 16.451 kJ/g. The experimental data obtained make it possible to use the obtained biochar from rice straw in the future as a biofertilizer to improve the characteristics of soils, as well as to use biochar obtained from rice husk to produce renewable fuel.
This article examines the effect of lignosulfonate binding of rice waste to oil waste to obtain activated carbon. Lignosulfonate was added to the mixture to produce briquetted activated carbon by processing rice residue (husk and straw) and oil sludge together. The mixture was carbonized and activated in a BR-12 NFT series high-temperature vacuum tube furnace with a length of 300 mm and a diameter of 60 mm and a heating section length of 200 mm in a quartz glass tube. Briquettes obtained by adding rice waste (husks and straw), oil sludge and lignosulfonate were placed in the kiln. Carbonation was carried out at a temperature of 500°C, activation was carried out at a temperature of 850°C in a ratio of 2: 1 with water vapor. The effect of the relationship of the addition of lignosulfonate binder to rice residue and oil sludge on the product properties was studied. The optimal ratio of co-treatment of the mixture was found in the ratio of rice residue: oil sludge: lignosulfonate = 9: 1: 2 (by weight). The adsorption activity of the obtained product on iodine, the total volume of pores on water, the mass fraction of moisture, the adsorption activity on methylene blue and the bulk density were studied. Activated carbon obtained from both rice straw and rice husk has high sorption properties. According to the results of experimental studies, activated carbon obtained by adding lignosulfonate to rice straw and oil sludge in a ratio of 9: 1: 2 corresponds to the brands BAС-A, WAC, BAC-Au.
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