By using the Zubarev nonequilibrium statistical operator method, and the Liouville equation with fractional derivatives, a generalized diffusion equation with fractional derivatives is obtained within the Renyi statistics. Averaging in generalized diffusion coefficient is performed with a power distribution with the Renyi parameter q.

Abstract. General expression for the thermodynamic potential of the model of semiinfinite jellium is obtained. By using this expression, the surface energy for infinite barrier model is calculated. The behavior of the surface energy and of chemical potential as functions of the Wigner-Seitz radius and the influence of the Coulomb interaction between electrons on the calculated values is studied. It is shown that taking into account the Coulomb interaction between electrons leads to growth of the surface energy. The surface energy is positivein the entire area of the Wigner-Seitz radius. It is shown that taking into account the Coulomb interaction between electrons leads to a decrease of the chemical potential.

The chemical potential of a metal film within the jellium model with taking into account the Coulomb interaction between electrons is calculated. The surface potential is modeled as the infinite rectangular potential well. The behavior of the chemical potential as a function of the film thickness is studied, the quantum size effect for this quantity is discovered. It is shown that taking into account the Coulomb interaction leads to a significant decrease of the chemical potential and to an enhancement of the quantum size effect.

Physical and technological principles of formation of clathrate structures for supramolecular electronics are given in this paper. It has been established that supramolecular nature of the "host-guest" conjunction, in general, and hierarchical architecture of the corresponding clathrates, in particular, provide realization of such an extraordinary effect as an optically or a magnetically controlled phenomenon of colossal "negative capacity" with a predicted frequency interval of manifestation, magnitude, and multiplicity. For the first time, the experimental confirmation of the behavior of the electretized fractal clathrate GaSe⟨β-CD⟨FeSO⟩⟩ as a dissipative element, which accumulates inductive energy, is demonstrated. A general approach for obtaining the generalized transport equations with fractional derivatives by using the Liouville equation with fractional derivatives for a system of classical particles and the Zubarev nonequilibrium statistical operator method within Renyi statistics is presented. New non-Markovian electrodiffusion equations for ions in a spatially heterogeneous medium with the fractal structure and a generalized Cattaneo-type diffusion equation taking into account the fractality of space-time are obtained. The model of subdiffusion impedance based on the Cattaneo equation with fractional derivatives is applied to multilayer nanostructures. Nyquist diagrams for different valuses of the parameter τ (delay time of a flow relative to a concentration gradient) and the subdiffusion coefficient D are calculated.

A system of electrons in a metal slab, which is described by the jellium model, is considered. The potential that forms a surface of the slab is modeled by the infinite square well potential. By using some approximations, the analytical expressions for effective interelectron interaction inside the slab and outside it are obtained.