Two novel macromolecular constitutional isomers have been self-assembled from previously unreported terpyridine ligands in a three-component system. The terpyridine ligands were synthesized in high yields via a key Suzuki coupling. Restrictions of the possible outcomes for self-assembly ultimately provided optimum conditions for isolation of either a molecular bowtie or its isomeric butterfly motif. These isomers have been characterized by ESI-MS, TWIM-MS, (1)H NMR, and (13)C NMR. Notably, these structural isomers have remarkably different drift times in ion mobility separation, corresponding to different sizes and shapes at high charge states.

A novel, efficient synthesis of cyclic carbonates from the reaction of epoxides and gaseous CO 2 under mild conditions (1 atm, rt to 45 • C) was achieved in reasonable yields (65-83%) by using N-methyltetrahydropyrimidine (MTHP) that facilitated efficient delivery of CO 2 from the gas phase to the reaction system.Scheme 1 Reversible fixation-release of CO 2 by amidine (MTHP).

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SynopsisA critical account has been presented of the recent investigation on the chemical modification of lignocellulosic sisal fibers. The molecular structure of the paracrystalline cellulose, which forms the major constituent of the fiber, was studied by x-ray diffraction technique. Scanning electron microscope examination of the multicellular structure, surface topology, and fracture morphology of the fiber was carried out. The mechanical properties of the sisal ultimate cell and the "technical" fiber have been investigated by means of a microextensometer and an Instron tensile tester, respectively.

The peroxovanadium species generated from V(2)O(5) and hydrogen peroxide, which is liberated from peroxy salts such as sodium perborate (SPB) or sodium percarbonate (SPC), transform aldehydes directly into esters in an alcoholic medium. Monoesters of diols have been achieved directly in one pot from aldehydes. High catalytic turnover number combined with inexpensive, easily available reagents and innocuous side products from the reaction make it a suitable alternative for the synthesis of esters from aldehydes.