Thick electrode with high-areal-capacity is a practical and promising strategy to increase the energy density of batteries, but development toward thick electrode is limited by the electrochemical performance, mechanical properties, and manufacturing approaches. In this work, we overcome these limitations and report an ultrathick electrode structure, called fiberaligned thick or FAT electrode, which offers a novel electrode design and a scalable manufacturing strategy for high-areal-capacity battery electrodes. The FAT electrode uses aligned carbon fibers to construct a through-thickness fiber-aligned electrode structure with features of high electrode material loading, low tortuosity, high electrical and thermal conductivity, and good compression property. The low tortuosity of FAT electrode enables fast electrolyte infusion and rapid electron/ion transport, exhibiting a higher capacity retention and lower charge transfer resistance than conventional slurry-casted thick electrode design.
Composite materials are known for their high stiffness and strength at lower weight as compared to conventional structural materials. Recently, there has been a growing interest in finding the new ways to decrease delamination failure, which is a life limiting factor of laminated composites. This review paper emphasizes on the effects of different reinforcement structures on mode I fracture toughness and possible ways to improve fracture toughness. A brief description on intrinsic and extrinsic mechanisms of crack growth has been discussed along with the earlier investigations and recent developments for mode I fracture toughness testing. Factors that affect the fracture toughness are also discussed. A brief knowledge of mode I fracture toughness of traditional and advanced fiber-reinforced composites is given, which could help researchers to understand fracture behaviors of composites and thus, it can help engineers to design composites with higher interlaminar strength.
This composite 3D-printing technology is based on a capillary effect through thermal gradient applied onto carbon fibers to allow deposited liquid polymers to simultaneously flow and become solid so as to form 3D structures. We also developed a robotic system consisting of a uniquely designed printing head and an automated robot arm, yielding a 3D printer that enables us to print a thermosetting composite with arbitrary shape and complex geometry on 2D and 3D substrates or in free space without supporting structures.
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