Self-assembled
graphene oxide lyotropic liquid crystal (GO LLC)
structures are mostly formed in aqueous medium; however, most GO derivatives
are water insoluble, so processing GO LLCs in water poses a practical
limitation. The use of polar aprotic solvent (like dimethyl sulfoxide)
for the formation of GO LLC structures would be interesting, because
it would allow incorporating additives, like photoinitiators or cross-linkers,
or blending with polymers that are insoluble in water, which hence
would expand its scope. The well-balanced electrostatic interaction
between DMSO and GO can promote and stabilize the GO nanosheets’
alignment even at lower concentrations. With this in mind, herein
we report mechanically robust, chlorine-tolerant, self-assembled nanostructured
GO membranes for precise molecular sieving. Small-angle X-ray scattering
and polarized optical microscopy confirmed the alignment of the modified
GO nanosheets in polar aprotic solvent, and the LLC structure was
effectively preserved even after cross-linking under UV light. We
found that the modified GO membranes exhibited considerably improved
salt rejection for monovalent ions (99%) and water flux (120 LMH)
as compared to the shear-aligned GO membrane, which is well supported
by forward osmosis simulation studies. Additionally, our simulation
studies indicated that water molecules traveled a longer path while
permeating through the GO membrane compared to the GO LLC membrane.
Consequently, salt ions permeate slowly across the GO LLC membrane,
yielding higher salt rejection than the GO membrane. This begins to
suggest strong electrostatic repulsion with the salt ions, causing
higher salt rejection in the GO LLC membrane. We foresee that the
ordered cross-linked GO sheets contributed to excellent mechanical
stability under a high-pressure, cross-flow, chlorine environment.
Overall, these membranes are easily scalable, exhibit good mechanical
stability, and represent a breakthrough for the potential use of polymerized
GO LLC membranes in practical water remediation applications.
This study investigates the nutritional status of school children on randomly selected Seven hundred thirty six children with their age range between 6 to 13 years taking Mid Day Meal (MDM) in govt. schools. This study is cross-sectional, consists the anthropometric measurements of body i.e., the height, weight and calculated BMI. To assess the nutritional status of children, the comparison has been drawn on the measurements between the collected data on children's body and the given ICMR (Indian Council of Medical Research) standard value. The study reveals the poor nutritional status of school children receiving mid day meal per day in rural scenario.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.