Carbonate-rich soils are characterized by great diversity in content of carbonate and non-carbonate mineral substances in soil substrate which largely influences soil properties. The study presents the analysis results of four soil profiles located at the area of Pieniny National Park. The aim of this study was to characterize and classify the soils developed from the mixture of carbonate and carbonate-rich rock material, formerly classified as pararendzinas. It was achieved by determination of morphological, physical, and chemical properties, as well as mineralogical composition of selected carbonate-rich soils occurring in the Polish part of the Pieniny Mts. Soils were classified as typical chernozemic rendzina (P1), typical eutrophic brown soils (P2, P4), as well as typical pararendzina (P3) according to Polish Soil Classification (2011).The parent material of studied soils P1, P2 and P4 were slope covers, with a dominant share of sandstone and minor share of limestone, whereas soil P3 was formed from variegated shale cut with multiple calcite veins. Soils were characterized by stable aggregate structure: crumby, angular blocky and subangular blocky. They were medium or strong skeletal, mostly with loam texture with great share of silt fraction. CaCO 3 content in genetic horizons ranged from 0.0 to 703.0 g⋅kg -1 . The reaction of studied soils was from weakly acidic to alkaline. Analysed soils were characterized by very high base saturation. Among determined exchangeable cations, Ca 2+ ions had the biggest share in all analysed profile. High base saturation, as well as high content of calcium carbonate was accompanied by content of organic matter and percentage content of clay fraction. Taking into consideration determined chemical and physical properties, it can be found that investigated soils were influenced by not only the in-situ weathering material but also by rock material which have been transported and deposited as a result of slope processes. Furthermore, the lack or lower content of CaCO 3 in surface and middle part of analysed soil profiles was most likely a result of the impoverishment of rock material during the transport on the slope.

Soil aggregate water stability is very important from both scientific and practical points of view. This stability is a critical factor in a soil's susceptibility to water erosion and, in turn, land degradation. The most popular measure of soil aggregate stability is the water resistance index (WRI), which is commonly measured using the wet‐sieving method. Using the laser diffraction method in order to observe changes in the median of the particle size distribution and determine soil aggregate stability was first proposed in 2010. However, the method was not suitable for weak aggregates. The aim of this study was to present a measure of aggregate stability using laser diffractometry, aggregate stability index (ASILD). Determination of the ASILD is based on the calculation of the directional coefficient of the straight line interpolated from 2 points: (a) the value calculated as the mean of the lower and upper nominal sieve sizes used for soil aggregate separation and (b) the median of the first measurement after the adding of the dry aggregates into the measuring system of the laser diffractometer. This proposed method for the calculation of the ASILD can be applied to very weak aggregates (i.e., aggregates that, in practice, are not at all water resistant). For weak and moderately stable aggregates, the correlation between ASILD and WRI is higher than 0.9. This method also enables differentiation between the water resistance of aggregates which, by the wet‐sieving method, are indistinguishable (i.e., those which have the maximum WRI).

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Due to the increasing amount of produced and accumulated wastes, a potential source of elements might be the global waste stream coming from the waste incineration process. As a result of this process, bottom ash, fly ash and air pollution control residues are produced. The goal of this study was to evaluate the raw material potential of the anthropogenic materials which are fly ashes from municipal waste incineration and municipal sewage sludge incineration, and the possibility for the recovery of metallic or other economically valuable elements by comparison of their chemical composition with the chemical composition of Earth materials (ultramafic, mafic and felsic igneous rocks, various sedimentary rocks), and with their lowest content in currently exploited ores. Fly ashes contain more valuable and critical elements when compared to Earth materials; however, they are less concentrated in comparison to the content in currently exploited ores. Since natural resources are becoming depleted, the costs of exploitation, mineral processing and related operations are increasing and the fly ashes are easily accessible. Cheap materials do not demand complicated treatment which might be considered as a future source of P, Zn, Sn, Cr, Pb, Au and Ag, and thus fulfilling the assumptions of close-loop economy and to maximize natural resources protection.

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