The development of new biosensor technologies and their active use as wearable devices have offered mobility and flexibility to conventional western medicine and personal fitness tracking. In the development of biosensors, transducers stand out as the main elements converting the signals sourced from a biological event into a detectable output. Combined with the suitable bio-receptors and the miniaturization of readout electronics, the functionality and design of the transducers play a key role in the construction of wearable devices for personal health control. Ever-growing research and industrial interest in new transducer technologies for point-of-care (POC) and wearable bio-detection have gained tremendous acceleration by the pandemic-induced digital health transformation. In this article, we provide a comprehensive review of transducers for biosensors and their wearable applications that empower users for the active tracking of biomarkers and personal health parameters.
A cerium oxide nanoparticles (CeO2-NPs)/graphene
oxide
(GO)/polyacrylamide (PAM) ternary composite was synthesized through
free-radical polymerization of acrylamide in the presence of CeO2 nanoparticles and GO in an aqueous system. The synthesized
composite material was characterized by X-ray diffraction (XRD), Fourier
transform infrared (FTIR) spectroscopy, scanning electron microscopy
(SEM), and energy-dispersive X-ray (EDX) spectroscopy techniques and
applied for the photocatalytic degradation of methylene blue (MB)
dye from an aqueous solution. Tauc’s model for direct transition
was used to model for the optical band gap. The key operating parameters
such as the amounts of CeO2-NPs and GO, pH, initial MB
concentration, type of light irradiation, and contact time have been
optimized to achieve the highest MB degradation percentage. The photocatalysis
process was pH-dependent, and the optimum pH value was found to be
12.0. Under UV-A light, 90% dye degradation occurred in 90 min. The
degradation of MB was also specified in terms of total organic carbon
(TOC) and chemical oxygen demand (COD). Free-radical capture experiments
were also performed to determine the role of radical species during
the photocatalytic oxidation process. The photocatalytic process showed
that the equilibrium data is in good agreement with the Langmuir–Hinshelwood
kinetic model. A rate constant of 0.0259 min–1 was
obtained. The hydrogel was also tested to assess its reusability,
which is an important key factor in practical wastewater treatment.
The photocatalytic activity only decreased to 75% after nine uses.
New generation nano-filler polymer composites have many applications including biomedical, electronic and maritime related applications because of their mechanical, electronic and optical properties. The properties of composites were investigated as a function of nano-filler content. Among these, tungsten disulfide (WS2) has the potential to be used as a component in electronic devices owing to its high electron mobility and easily tunable optical band gap energy. Tungsten disulfide (WS2)- Polyacrylamide (PAAm) composite was prepared using free radical co-polymerization and wet laboratory methods with WS2 content. Composites were characterized for mechanical and optical properties using an Elasticity Instrument and UV-vis Spectrophotometer, respectively. Elastic modulus was modeled by a statistical thermodynamics model. Tauc’s and Urbach’s Tail model for direct transition were used to model for the optical band gap. In this study, the swelling and WS2 effect on the optical band gap and elasticity of WS2 - PAAm composites were investigated. It was observed that the elasticity presented a reversed behavior of optical band gap energies with respect to WS2 content. For the applications of nano-filler doped polymer composites in flexible electronic devices, WS2 content strongly influences the mechanical and optical properties.
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